Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| Kinetic and thermodynamic studies of biomass pseudo-components under thermo-oxidative degradation conditions using asymmetric function of Bi-Gaussian as deconvolution technique | |
Li, Weizhen1,2,3 ; Huang, Yanqin2; Liu, Huacai2; Zhang, Yan4; Jiang, Yang2,3; Wang, Yan1,5; Wan, Junfeng1; Yin, Xiuli2
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| 2022-04-01 | |
| Source Publication | RENEWABLE ENERGY
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| ISSN | 0960-1481 |
| Volume | 188Pages:491-503 |
| Corresponding Author | Wang, Yan(wangyan371@zzu.edu.cn) |
| Abstract | This work aimed at investigating the kinetic and thermodynamic characteristics of components of pine sawdust (PS), edible fungi spent substrate (FVSS) and their blend during thermo-oxidative degradation. The novelty focused on applying deconvolution technique to distinguish an overlapped peak into three individual peaks corresponding to pseudo-hemicellulose, pseudo-cellulose and pseudo-lignin, respectively. Particularly, the function of Bi-Gaussian was employed to capture the asymmetric reaction shapes. Mass loss was recorded using a thermal analyzer at heating rates of 10, 20 and 30 K min-1 in air atmosphere. Methods of Starink and master-plots were used for estimating kinetic triplet. The average activation energies of FVSS are lower than PS, with an order of pseudo-lignin > pseudohemicellulose > pseudo-cellulose corresponding to the ranges of 211.70-342.78, 139.00-172.53 and 128.08-146.99 kJ mol-1, respectively. The pre-exponential factor are all higher than E+10 s-1 demonstrating some simple complex chemical reactions occurred. Models of D2 and A1 dominate the degradation of pseudo-hemicellulose and pseudo-cellulose, respectively, in PS and the blend. The average values of DS, DH and DG are -51.62-146.31 J mol-1, 122.99-335 kJ mol-1 and 78 144.87-216.59 kJ mol-1, showing the non-spontaneous process and need energy to maintain. (c) 2022 Elsevier Ltd. All rights reserved. |
| Keyword | Biomass Pseudo-component Thermo-oxidative degradation Deconvolution Bi-Gaussian Kinetic and thermodynamic parameters |
| DOI | 10.1016/j.renene.2022.02.024 |
| WOS Keyword | ACTIVATION-ENERGY MODEL ; SOLID-STATE REACTIONS ; NONISOTHERMAL KINETICS ; THERMOGRAVIMETRIC ANALYSIS ; TG-FTIR ; COMBUSTION CHARACTERISTICS ; PYROLYSIS CHARACTERISTICS ; LIGNOCELLULOSIC BIOMASS ; THERMAL-DECOMPOSITION ; MIXTURE MODEL |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | National Natural Science Foundation of China[51776207] ; High-tech Industrialization Cooperation Program of Jilin Province ; Chinese Academy of Sciences[2021SYHZ0014] ; Strategic Priority Research Program of Chinese Academy of Sciences[XDA21060600] ; Natural Science Foundation of Guangdong Province, China[2019A1515011535] ; Science and Technology Program of Guangzhou[202102080357] ; Science and Technology Program of Guangzhou[201904010098] |
| WOS Research Area | Science & Technology - Other Topics ; Energy & Fuels |
| Funding Organization | National Natural Science Foundation of China ; High-tech Industrialization Cooperation Program of Jilin Province ; Chinese Academy of Sciences ; Strategic Priority Research Program of Chinese Academy of Sciences ; Natural Science Foundation of Guangdong Province, China ; Science and Technology Program of Guangzhou |
| WOS Subject | Green & Sustainable Science & Technology ; Energy & Fuels |
| WOS ID | WOS:000808568500002 |
| Publisher | PERGAMON-ELSEVIER SCIENCE LTD |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/36853 |
| Collection | 中国科学院广州能源研究所 |
| Corresponding Author | Wang, Yan |
| Affiliation | 1.Zhengzhou Univ, Coll Chem Engn, Zhengzhou 450001, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China 3.Zibo Energy Res Inst, Zibo 255035, Peoples R China 4.South China Agr Univ, Coll Mat & Energy, Guangzhou 510642, Peoples R China 5.Coll Chem Engn, 100 Sci Ave, Zhengzhou 450001, Henan, Peoples R China |
| First Author Affilication | GuangZhou Institute of Energy Conversion,Chinese Academy of Sciences |
| Recommended Citation GB/T 7714 | Li, Weizhen,Huang, Yanqin,Liu, Huacai,et al. Kinetic and thermodynamic studies of biomass pseudo-components under thermo-oxidative degradation conditions using asymmetric function of Bi-Gaussian as deconvolution technique[J]. RENEWABLE ENERGY,2022,188:491-503. |
| APA | Li, Weizhen.,Huang, Yanqin.,Liu, Huacai.,Zhang, Yan.,Jiang, Yang.,...&Yin, Xiuli.(2022).Kinetic and thermodynamic studies of biomass pseudo-components under thermo-oxidative degradation conditions using asymmetric function of Bi-Gaussian as deconvolution technique.RENEWABLE ENERGY,188,491-503. |
| MLA | Li, Weizhen,et al."Kinetic and thermodynamic studies of biomass pseudo-components under thermo-oxidative degradation conditions using asymmetric function of Bi-Gaussian as deconvolution technique".RENEWABLE ENERGY 188(2022):491-503. |
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