Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| One-pot conversion of biomass-derived levulinic acid to furanic biofuel 2-methyltetrahydrofuran over bimetallic NiCo/?-Al2O3 catalysts | |
Gu, Canshuo1,4; Chen, Lungang2,6; Liu, Yong3; Zhang, Xinghua2 ; Liu, Jianguo2; Zhang, Qi2; Wang, Chenguang1,5; Ma, Longlong2
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| 2022-05-01 | |
| Source Publication | MOLECULAR CATALYSIS
 |
| ISSN | 2468-8231 |
| Volume | 524Pages:9 |
| Corresponding Author | Chen, Lungang(chenlg@seu.edu.cn) |
| Abstract | The production of furanic biofuel 2-methyltetrahydrofuran (2-MTHF) has been studied by hydrodeoxygenation of biomass-derived levulinic acid (LA) over bimetallic NiCo/gamma-Al2O3 catalyst. The contents of Ni and Co in NiCo/gamma-Al2O3 were investigated. The Ni5Co25/gamma-Al2O3 catalyst gave high activity in hydrodeoxygenation of LA with a 73.4% yield of 2-MTHF under optimal conditions. The crystal phase, valence states, acidity and basicity of catalysts were measured by multiple characterizations to understand the relationships among 2-MTHF yields and catalyst properties. XPS characterization revealed that the number of metal oxides increased on bimetallic catalysts while the reduced metals occupied on monometallic catalysts. The bimetallic catalysts also presented increased acidity than that of monometallic catalysts. These distinct properties were also observed among bimetallic catalysts with different contents of Ni and Co, which were responsible for different performances. Besides, the solvent effect on the structure of 1,4-pentanediol, which was further converted to 2-methyltetrahydrofuran, was disclosed by molecular dynamics simulations. |
| Keyword | Biomass Furanic biofuel Levulinic acid 2-methyltetrahydrofuran Molecular Dynamics simulation |
| DOI | 10.1016/j.mcat.2022.112317 |
| WOS Keyword | GAMMA-VALEROLACTONE ; HYDROGENATION ; TRANSFORMATION ; EFFICIENT ; 1,4-PENTANEDIOL ; NANOCRYSTALS ; ZEOLITE ; ALKANES |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | National Key R&D Program of China[2019YFD1100601] ; National Natural Science Foun-dation of China[21878290] ; Program of Innovation Acad-emy for Green Manufacture, Chinese Academy of Sciences[IAGM2020C21] |
| WOS Research Area | Chemistry |
| Funding Organization | National Key R&D Program of China ; National Natural Science Foun-dation of China ; Program of Innovation Acad-emy for Green Manufacture, Chinese Academy of Sciences |
| WOS Subject | Chemistry, Physical |
| WOS ID | WOS:000804789100003 |
| Publisher | ELSEVIER |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/36785 |
| Collection | 中国科学院广州能源研究所 |
| Corresponding Author | Chen, Lungang |
| Affiliation | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China 2.Southeast Univ, Sch Energy & Environm, Key Lab Energy Thermal Convers & Control, Minist Educ, Nanjing 210096, Peoples R China 3.Nanchang Univ, Sch Resources & Environm, Key Lab Poyang Lake Environm & Resource Utilizat, Minist Educ, Nanchang 330031, Peoples R China 4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 5.Chinese Acad Sci, Innovat Acad Green Manufacture, Beijing 100049, Peoples R China 6.Southeast Univ, Sch energy & Environm, Nanjing 210096, Peoples R China |
| First Author Affilication | GuangZhou Institute of Energy Conversion,Chinese Academy of Sciences |
| Recommended Citation GB/T 7714 | Gu, Canshuo,Chen, Lungang,Liu, Yong,et al. One-pot conversion of biomass-derived levulinic acid to furanic biofuel 2-methyltetrahydrofuran over bimetallic NiCo/?-Al2O3 catalysts[J]. MOLECULAR CATALYSIS,2022,524:9. |
| APA | Gu, Canshuo.,Chen, Lungang.,Liu, Yong.,Zhang, Xinghua.,Liu, Jianguo.,...&Ma, Longlong.(2022).One-pot conversion of biomass-derived levulinic acid to furanic biofuel 2-methyltetrahydrofuran over bimetallic NiCo/?-Al2O3 catalysts.MOLECULAR CATALYSIS,524,9. |
| MLA | Gu, Canshuo,et al."One-pot conversion of biomass-derived levulinic acid to furanic biofuel 2-methyltetrahydrofuran over bimetallic NiCo/?-Al2O3 catalysts".MOLECULAR CATALYSIS 524(2022):9. |
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