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Improved production of levoglucosan and levoglucosenone from acid-impregnated cellulose via fast pyrolysis
Xu, Feixiang1; Luo, Jiangchen1; Jiang, Liqun1,2,3; Zhao, Zengli1
2022-01-11
Source PublicationCELLULOSE
ISSN0969-0239
Pages10
Corresponding AuthorJiang, Liqun(lqjiang@ms.giec.ac.cn)
AbstractIn this research, the production of levoglucosan (LG) and levoglucosenone (LGO) was improved from acid-impregnated cellulose via fast pyrolysis. Thermogravimetric and kinetic analysis disclosed the production formation mechanism. The impregnation of acid could reduce the activation energy and lower the reaction temperature. Furthermore, the yield of LG from H3PO4- and H2SO4-impregnated cellulose increased significantly (26.4-35.8 wt%) compared with that of pure cellulose (7.5 wt%) pyrolysis at 300 degrees C. At 350 degrees C, 0.1 wt% H3PO4-impregnated cellulose gave a maximum LGO yield (18.3 wt%) via pyrolysis, which increased 36 times concerning that of cellulose without acid impregnation (0.5 wt%). This study exhibited great potential for industrial LG and LGO production from cellulose at low temperatures.
KeywordCellulose Catalytic pyrolysis Levoglucosan Levoglucosenone
DOI10.1007/s10570-021-04387-4
WOS KeywordCATALYTIC FAST PYROLYSIS ; CO-PYROLYSIS ; BIOMASS ; DEHYDRATION ; KINETICS
Indexed BySCI
Language英语
Funding ProjectGuangdong Basic and Applied Basic Research Foundation[2021A1515012063] ; Foundation of State Key Laboratory of Utilization of Woody Oil Resource[GZKF202116] ; Youth Innovation Promotion Association of CAS[2021350] ; Youth Innovation Promotion Association of CAS[2020GDASYL-20200102010] ; Youth Innovation Promotion Association of CAS[2020GDASYL-20200102009] ; Guangdong Academy of Sciences, China
WOS Research AreaMaterials Science ; Polymer Science
Funding OrganizationGuangdong Basic and Applied Basic Research Foundation ; Foundation of State Key Laboratory of Utilization of Woody Oil Resource ; Youth Innovation Promotion Association of CAS ; Guangdong Academy of Sciences, China
WOS SubjectMaterials Science, Paper & Wood ; Materials Science, Textiles ; Polymer Science
WOS IDWOS:000741277500006
PublisherSPRINGER
Citation statistics
Cited Times:10[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/35645
Collection中国科学院广州能源研究所
Corresponding AuthorJiang, Liqun
Affiliation1.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou 510640, Peoples R China
2.Guangdong Acad Sci, Inst Biol & Med Engn, Guangzhou 510316, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
First Author AffilicationGuangZhou Institute of Energy Conversion,Chinese Academy of Sciences
Recommended Citation
GB/T 7714
Xu, Feixiang,Luo, Jiangchen,Jiang, Liqun,et al. Improved production of levoglucosan and levoglucosenone from acid-impregnated cellulose via fast pyrolysis[J]. CELLULOSE,2022:10.
APA Xu, Feixiang,Luo, Jiangchen,Jiang, Liqun,&Zhao, Zengli.(2022).Improved production of levoglucosan and levoglucosenone from acid-impregnated cellulose via fast pyrolysis.CELLULOSE,10.
MLA Xu, Feixiang,et al."Improved production of levoglucosan and levoglucosenone from acid-impregnated cellulose via fast pyrolysis".CELLULOSE (2022):10.
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