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Optimization of biodiesel production from trap grease via acid catalysis
Wang, Zhong-Ming2,3; Lee, Jin-Suk1; Park, Ji-Yeon1; Wu, Chuang-Zhi2; Yuan, Zhen-Hong2
2008-07-01
Source PublicationKOREAN JOURNAL OF CHEMICAL ENGINEERING
ISSN0256-1115
Volume25Issue:4Pages:670-674
Corresponding Authorbmjslee@kier.re.kr
AbstractAs a kind of waste collected from restaurants, trap grease is a chemically challenging feedstock for biodiesel production for its high free fatty acid (FFA) content. A central composite design was used to evaluate the effect of methanol quantity, acid concentration and reaction time on the synthesis of biodiesel from the trap grease with 50% free fatty acid, while the reaction temperature was selected at 95 degrees C. Using response surface methodology, a quadratic polynomial equation was obtained for ester content by multiple regression analysis. Verification experiments confirmed the validity of the predicted model. To achieve the highest ester content of crude biodiesel (89.67%), the critical values of the three variables were 35.00 (methanol-to-oil molar ratio), 11.27 wt% (catalyst concentration based on trap grease) and 4.59 h (reaction time). The crude biodiesel could be purified by a second distillation to meet the requirement of biodiesel specification of Korea.
SubtypeArticle
Other AbstractAs a kind of waste collected from restaurants, trap grease is a chemically challenging feedstock for biodiesel production for its high free fatty acid (FFA) content. A central composite design was used to evaluate the effect of methanol quantity, acid concentration and reaction time on the synthesis of biodiesel from the trap grease with 50% free fatty acid, while the reaction temperature was selected at 95 degrees C. Using response surface methodology, a quadratic polynomial equation was obtained for ester content by multiple regression analysis. Verification experiments confirmed the validity of the predicted model. To achieve the highest ester content of crude biodiesel (89.67%), the critical values of the three variables were 35.00 (methanol-to-oil molar ratio), 11.27 wt% (catalyst concentration based on trap grease) and 4.59 h (reaction time). The crude biodiesel could be purified by a second distillation to meet the requirement of biodiesel specification of Korea.
KeywordBiodiesel Trap Grease Acid Catalysis Central Composite Design Response Surface Methodology
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
WOS Subject ExtendedChemistry ; Engineering
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WOS KeywordOIL
Indexed BySCI
Language英语
Funding OrganizationKorea New and Renewable Energy Center (KNREC) ; Korean Ministry of Commerce, Industry and Energy (KMOCIE)
WOS SubjectChemistry, Multidisciplinary ; Engineering, Chemical
WOS IDWOS:000258549600008
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Cited Times:59[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/3418
Collection中国科学院广州能源研究所
Affiliation1.Korea Inst Energy Res, Taejon 305343, South Korea
2.CAS, Guangzhou Inst Energy Convers, Beijing, Peoples R China
3.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Wang, Zhong-Ming,Lee, Jin-Suk,Park, Ji-Yeon,et al. Optimization of biodiesel production from trap grease via acid catalysis[J]. KOREAN JOURNAL OF CHEMICAL ENGINEERING,2008,25(4):670-674.
APA Wang, Zhong-Ming,Lee, Jin-Suk,Park, Ji-Yeon,Wu, Chuang-Zhi,&Yuan, Zhen-Hong.(2008).Optimization of biodiesel production from trap grease via acid catalysis.KOREAN JOURNAL OF CHEMICAL ENGINEERING,25(4),670-674.
MLA Wang, Zhong-Ming,et al."Optimization of biodiesel production from trap grease via acid catalysis".KOREAN JOURNAL OF CHEMICAL ENGINEERING 25.4(2008):670-674.
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