Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
Optimization of biodiesel production from trap grease via acid catalysis | |
Wang, Zhong-Ming2,3; Lee, Jin-Suk1; Park, Ji-Yeon1; Wu, Chuang-Zhi2; Yuan, Zhen-Hong2 | |
2008-07-01 | |
Source Publication | KOREAN JOURNAL OF CHEMICAL ENGINEERING |
ISSN | 0256-1115 |
Volume | 25Issue:4Pages:670-674 |
Corresponding Author | bmjslee@kier.re.kr |
Abstract | As a kind of waste collected from restaurants, trap grease is a chemically challenging feedstock for biodiesel production for its high free fatty acid (FFA) content. A central composite design was used to evaluate the effect of methanol quantity, acid concentration and reaction time on the synthesis of biodiesel from the trap grease with 50% free fatty acid, while the reaction temperature was selected at 95 degrees C. Using response surface methodology, a quadratic polynomial equation was obtained for ester content by multiple regression analysis. Verification experiments confirmed the validity of the predicted model. To achieve the highest ester content of crude biodiesel (89.67%), the critical values of the three variables were 35.00 (methanol-to-oil molar ratio), 11.27 wt% (catalyst concentration based on trap grease) and 4.59 h (reaction time). The crude biodiesel could be purified by a second distillation to meet the requirement of biodiesel specification of Korea. |
Subtype | Article |
Other Abstract | As a kind of waste collected from restaurants, trap grease is a chemically challenging feedstock for biodiesel production for its high free fatty acid (FFA) content. A central composite design was used to evaluate the effect of methanol quantity, acid concentration and reaction time on the synthesis of biodiesel from the trap grease with 50% free fatty acid, while the reaction temperature was selected at 95 degrees C. Using response surface methodology, a quadratic polynomial equation was obtained for ester content by multiple regression analysis. Verification experiments confirmed the validity of the predicted model. To achieve the highest ester content of crude biodiesel (89.67%), the critical values of the three variables were 35.00 (methanol-to-oil molar ratio), 11.27 wt% (catalyst concentration based on trap grease) and 4.59 h (reaction time). The crude biodiesel could be purified by a second distillation to meet the requirement of biodiesel specification of Korea. |
Keyword | Biodiesel Trap Grease Acid Catalysis Central Composite Design Response Surface Methodology |
WOS Headings | Science & Technology ; Physical Sciences ; Technology |
WOS Subject Extended | Chemistry ; Engineering |
URL | 查看原文 |
WOS Keyword | OIL |
Indexed By | SCI |
Language | 英语 |
Funding Organization | Korea New and Renewable Energy Center (KNREC) ; Korean Ministry of Commerce, Industry and Energy (KMOCIE) |
WOS Subject | Chemistry, Multidisciplinary ; Engineering, Chemical |
WOS ID | WOS:000258549600008 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.giec.ac.cn/handle/344007/3418 |
Collection | 中国科学院广州能源研究所 |
Affiliation | 1.Korea Inst Energy Res, Taejon 305343, South Korea 2.CAS, Guangzhou Inst Energy Convers, Beijing, Peoples R China 3.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
Recommended Citation GB/T 7714 | Wang, Zhong-Ming,Lee, Jin-Suk,Park, Ji-Yeon,et al. Optimization of biodiesel production from trap grease via acid catalysis[J]. KOREAN JOURNAL OF CHEMICAL ENGINEERING,2008,25(4):670-674. |
APA | Wang, Zhong-Ming,Lee, Jin-Suk,Park, Ji-Yeon,Wu, Chuang-Zhi,&Yuan, Zhen-Hong.(2008).Optimization of biodiesel production from trap grease via acid catalysis.KOREAN JOURNAL OF CHEMICAL ENGINEERING,25(4),670-674. |
MLA | Wang, Zhong-Ming,et al."Optimization of biodiesel production from trap grease via acid catalysis".KOREAN JOURNAL OF CHEMICAL ENGINEERING 25.4(2008):670-674. |
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