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Experimental Investigation on Propane Hydrate Dissociation by High Concentration Methanol and Ethylene Glycol Solution Injection
Dong, Fuhai1,3; Zang, Xiaoya1; Li, Dongliang1; Fan, Shuanshi2; Liang, Deqing1
2009-03-01
Source PublicationENERGY & FUELS
ISSN0887-0624
Volume23Issue:Sp. Iss. SIPages:1563-1567
Corresponding Authorliangdq@ms.giec.ac.cn
AbstractThe dissociation behaviors of propane hydrate by high concentration alcohols inhibitors injection were investigated. Methanol (30.0, 60.1, 80.2, and 99.5 wt %) and ethylene glycol (30.0, 60.1, 69.8, 80.2, and 99.5 wt %) solution were injected, respectively, as alcohols inhibitors in 3.5 L transparent reactor. It is shown that the average dissociation rates of propane hydrate injecting methanol and ethylene glycol solution are 0.02059-0.04535 and 0.0302-0.0606 mol.min(-1).L(-1), respectively. The average dissociation rates increase with the mass concentration increase of alcohols solution, and it is the biggest when 99.5 wt % ethylene glycol solution was injected. The presence of alcohols accelerates gas hydrate dissociation and reduces the total need of external energy to dissociate the hydrates. Density differences act as driving force, causing the acceleration effects of ethylene glycol on dissociation behaviors of propane hydrate are better than that of methanol with the same injecting flux and mass concentration.
SubtypeArticle
Other AbstractThe dissociation behaviors of propane hydrate by high concentration alcohols inhibitors injection were investigated. Methanol (30.0, 60.1, 80.2, and 99.5 wt %) and ethylene glycol (30.0, 60.1, 69.8, 80.2, and 99.5 wt %) solution were injected, respectively, as alcohols inhibitors in 3.5 L transparent reactor. It is shown that the average dissociation rates of propane hydrate injecting methanol and ethylene glycol solution are 0.02059-0.04535 and 0.0302-0.0606 mol.min(-1).L-1, respectively. The average dissociation rates increase with the mass concentration increase of alcohols solution, and it is the biggest when 99.5 wt % ethylene glycol solution was injected. The presence of alcohols accelerates gas hydrate dissociation and reduces the total need of external energy to dissociate the hydrates. Density differences act as driving force, causing the acceleration effects of ethylene glycol on dissociation behaviors of propane hydrate are better than that of methanol with the same injecting flux and mass concentration.
KeywordGas Resource Mixtures Energy
WOS HeadingsScience & Technology ; Technology
DOI10.1021/ef800660m
WOS Subject ExtendedEnergy & Fuels ; Engineering
URL查看原文
WOS KeywordGAS ; RESOURCE ; MIXTURES ; ENERGY
Indexed BySCI
Language英语
Funding OrganizationNational Natural Science Foundation of China [50676097]; National Basic Research Program of China [2009CB219504]
WOS SubjectEnergy & Fuels ; Engineering, Chemical
WOS IDWOS:000265439000056
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Cited Times:46[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/3350
Collection中国科学院广州能源研究所
Affiliation1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy & Gas Hydrate, Guangzhou 510640, Guangdong, Peoples R China
2.S China Univ Technol, Key Lab Enhanced Heat Transfer & Energy Conservat, MOE, Guangzhou 510640, Guangdong, Peoples R China
3.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Dong, Fuhai,Zang, Xiaoya,Li, Dongliang,et al. Experimental Investigation on Propane Hydrate Dissociation by High Concentration Methanol and Ethylene Glycol Solution Injection[J]. ENERGY & FUELS,2009,23(Sp. Iss. SI):1563-1567.
APA Dong, Fuhai,Zang, Xiaoya,Li, Dongliang,Fan, Shuanshi,&Liang, Deqing.(2009).Experimental Investigation on Propane Hydrate Dissociation by High Concentration Methanol and Ethylene Glycol Solution Injection.ENERGY & FUELS,23(Sp. Iss. SI),1563-1567.
MLA Dong, Fuhai,et al."Experimental Investigation on Propane Hydrate Dissociation by High Concentration Methanol and Ethylene Glycol Solution Injection".ENERGY & FUELS 23.Sp. Iss. SI(2009):1563-1567.
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