Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
Experimental Investigation on Propane Hydrate Dissociation by High Concentration Methanol and Ethylene Glycol Solution Injection | |
Dong, Fuhai1,3; Zang, Xiaoya1; Li, Dongliang1; Fan, Shuanshi2; Liang, Deqing1 | |
2009-03-01 | |
Source Publication | ENERGY & FUELS |
ISSN | 0887-0624 |
Volume | 23Issue:Sp. Iss. SIPages:1563-1567 |
Corresponding Author | liangdq@ms.giec.ac.cn |
Abstract | The dissociation behaviors of propane hydrate by high concentration alcohols inhibitors injection were investigated. Methanol (30.0, 60.1, 80.2, and 99.5 wt %) and ethylene glycol (30.0, 60.1, 69.8, 80.2, and 99.5 wt %) solution were injected, respectively, as alcohols inhibitors in 3.5 L transparent reactor. It is shown that the average dissociation rates of propane hydrate injecting methanol and ethylene glycol solution are 0.02059-0.04535 and 0.0302-0.0606 mol.min(-1).L(-1), respectively. The average dissociation rates increase with the mass concentration increase of alcohols solution, and it is the biggest when 99.5 wt % ethylene glycol solution was injected. The presence of alcohols accelerates gas hydrate dissociation and reduces the total need of external energy to dissociate the hydrates. Density differences act as driving force, causing the acceleration effects of ethylene glycol on dissociation behaviors of propane hydrate are better than that of methanol with the same injecting flux and mass concentration. |
Subtype | Article |
Other Abstract | The dissociation behaviors of propane hydrate by high concentration alcohols inhibitors injection were investigated. Methanol (30.0, 60.1, 80.2, and 99.5 wt %) and ethylene glycol (30.0, 60.1, 69.8, 80.2, and 99.5 wt %) solution were injected, respectively, as alcohols inhibitors in 3.5 L transparent reactor. It is shown that the average dissociation rates of propane hydrate injecting methanol and ethylene glycol solution are 0.02059-0.04535 and 0.0302-0.0606 mol.min(-1).L-1, respectively. The average dissociation rates increase with the mass concentration increase of alcohols solution, and it is the biggest when 99.5 wt % ethylene glycol solution was injected. The presence of alcohols accelerates gas hydrate dissociation and reduces the total need of external energy to dissociate the hydrates. Density differences act as driving force, causing the acceleration effects of ethylene glycol on dissociation behaviors of propane hydrate are better than that of methanol with the same injecting flux and mass concentration. |
Keyword | Gas Resource Mixtures Energy |
WOS Headings | Science & Technology ; Technology |
DOI | 10.1021/ef800660m |
WOS Subject Extended | Energy & Fuels ; Engineering |
URL | 查看原文 |
WOS Keyword | GAS ; RESOURCE ; MIXTURES ; ENERGY |
Indexed By | SCI |
Language | 英语 |
Funding Organization | National Natural Science Foundation of China [50676097]; National Basic Research Program of China [2009CB219504] |
WOS Subject | Energy & Fuels ; Engineering, Chemical |
WOS ID | WOS:000265439000056 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.giec.ac.cn/handle/344007/3350 |
Collection | 中国科学院广州能源研究所 |
Affiliation | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy & Gas Hydrate, Guangzhou 510640, Guangdong, Peoples R China 2.S China Univ Technol, Key Lab Enhanced Heat Transfer & Energy Conservat, MOE, Guangzhou 510640, Guangdong, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
Recommended Citation GB/T 7714 | Dong, Fuhai,Zang, Xiaoya,Li, Dongliang,et al. Experimental Investigation on Propane Hydrate Dissociation by High Concentration Methanol and Ethylene Glycol Solution Injection[J]. ENERGY & FUELS,2009,23(Sp. Iss. SI):1563-1567. |
APA | Dong, Fuhai,Zang, Xiaoya,Li, Dongliang,Fan, Shuanshi,&Liang, Deqing.(2009).Experimental Investigation on Propane Hydrate Dissociation by High Concentration Methanol and Ethylene Glycol Solution Injection.ENERGY & FUELS,23(Sp. Iss. SI),1563-1567. |
MLA | Dong, Fuhai,et al."Experimental Investigation on Propane Hydrate Dissociation by High Concentration Methanol and Ethylene Glycol Solution Injection".ENERGY & FUELS 23.Sp. Iss. SI(2009):1563-1567. |
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