Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
Highly Efficient Conversion of Xylose to Furfural in a Water-MIBK System Catalyzed by Magnetic Carbon-Based Solid Acid | |
Qi, Zhiqiang1,2; Wang, Qiong2; Liang, Cuiyi2; Yue, Jun3; Liu, Shuna2; Ma, Shexia4; Wang, Xiaohan2; Wang, Zhongming2; Li, Zhihe1; Qi, Wei2 | |
2020-09-30 | |
发表期刊 | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH |
ISSN | 0888-5885 |
卷号 | 59期号:39页码:17046-17056 |
通讯作者 | Li, Zhihe(lizhihe@sdut.edu.cn) ; Qi, Wei(qiwei@ms.giec.ac.cn) |
摘要 | In this work, the conversion of xylose to furfural (FF) was effectively achieved in a water-MIBK biphasic solvent system over a synthesized magnetic carbon-based solid acid catalyst (MMCSA). The effect of various reaction conditions was studied on the dehydration of xylose, and the highest FF yield of 79.04% was obtained. Byproducts in the reaction process were identified by high-performance liquid chromatography-mass spectrometry (LC-MS), which provides insights into the reaction pathway of the xylose conversion to FF over the current catalyst. The observed deactivation of the catalyst at high temperature (190 degrees C) was addressed by its regeneration with concentrated sulfuric acid (98 wt %). A comparable FF yield (73.74%) was achieved over the regenerated MMCSA. The possible deactivation- regeneration mechanism of this catalyst has also been proposed. Overall, this work provides a valuable basis for the efficient synthesis of FF by solid acid-catalyzed conversion of xylose or hemicellulose. |
DOI | 10.1021/acs.iecr.9b06349 |
关键词[WOS] | CORNCOB SACCHARIFICATION ; SELECTIVE CONVERSION ; PROMISING PLATFORM ; BIPHASIC SYSTEM ; BIOMASS ; HYDROLYSIS ; CELLULOSE ; FUEL ; PRETREATMENT ; DEHYDRATION |
收录类别 | SCI |
语种 | 英语 |
资助项目 | National Natural Science Foundation of China[51676193] ; National Natural Science Foundation of China[51861145103] ; National Natural Science Foundation of China[2171101430] ; National Key Research and Development Program of China[2018YFC1901201] ; Youth Innovation Promotion Association, CAS[2017401] ; Municipal Science and Technology Program of Guangzhou[201804010187] ; National Natural Science Foundation of China (NSFC)[21811530627] ; Dutch Research Council (NWO)[21811530627] ; NWO[040.21.006] ; Foundation of State Key Laboratory of Coal Combustion[FSKLCCA1804] |
WOS研究方向 | Engineering |
项目资助者 | National Natural Science Foundation of China ; National Key Research and Development Program of China ; Youth Innovation Promotion Association, CAS ; Municipal Science and Technology Program of Guangzhou ; National Natural Science Foundation of China (NSFC) ; Dutch Research Council (NWO) ; NWO ; Foundation of State Key Laboratory of Coal Combustion |
WOS类目 | Engineering, Chemical |
WOS记录号 | WOS:000577113500012 |
出版者 | AMER CHEMICAL SOC |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.giec.ac.cn/handle/344007/32190 |
专题 | 中国科学院广州能源研究所 |
通讯作者 | Li, Zhihe; Qi, Wei |
作者单位 | 1.Shandong Univ Technol, Shandong Res Ctr Engn & Technol Clean Energy, Sch Agr Engn & Food Sci, Zibo 255000, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China 3.Univ Groningen, Dept Chem Engn, Engn & Technol Inst Groningen, NL-9747 AG Groningen, Netherlands 4.Minist Ecol & Environm, State Environm Protect Key Lab Environm Protect H, South China Inst Environm Sci, Guangzhou 510535, Guangdong, Peoples R China |
第一作者单位 | 中国科学院广州能源研究所 |
推荐引用方式 GB/T 7714 | Qi, Zhiqiang,Wang, Qiong,Liang, Cuiyi,et al. Highly Efficient Conversion of Xylose to Furfural in a Water-MIBK System Catalyzed by Magnetic Carbon-Based Solid Acid[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2020,59(39):17046-17056. |
APA | Qi, Zhiqiang.,Wang, Qiong.,Liang, Cuiyi.,Yue, Jun.,Liu, Shuna.,...&Qi, Wei.(2020).Highly Efficient Conversion of Xylose to Furfural in a Water-MIBK System Catalyzed by Magnetic Carbon-Based Solid Acid.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,59(39),17046-17056. |
MLA | Qi, Zhiqiang,et al."Highly Efficient Conversion of Xylose to Furfural in a Water-MIBK System Catalyzed by Magnetic Carbon-Based Solid Acid".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 59.39(2020):17046-17056. |
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