Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| Synthesis and Configurational Character Study of Novel Structural Isomers Based on Pyrene-Imidazole | |
| Liu, Yu-Long1,2; Yang, Liu1; Guo, You-Quan3; Xu, Guo-Qiang1; Qu, Bin1,2; Fu, Ying1 | |
| 2019-06-02 | |
| Source Publication | MOLECULES
 |
| ISSN | 1420-3049 |
| Volume | 24Issue:12Pages:11 |
| Corresponding Author | Fu, Ying(fuying@neau.edu.cn) |
| Abstract | Isomers provide more possibilities for the structure of organic compounds. Molecular structures determine their corresponding properties, therefore the intrinsic relationship between structure and properties of isomers is of great research value. Isomers with a stable structure and excellent performance possess more potential for development and application. In this paper, we design and synthesize structural isomers with different molecular symmetries based on the asymmetric structure of imidazole and the symmetrical structure of pyrene. Isomers with stable molecular structures can be obtained by a simple and efficient one-pot reaction, involving axisymmetric configuration and centrosymmetric configuration. Using this click-like reaction, the structure of target molecules is controllable and adjustable. Furthermore, the effect of molecular configurations on molecular stacking of crystal is studied. The variation of the optical and thermal properties, the optimized structures, and orbital distributions of isomers depends on different molecular geometry with different symmetry, which are revealed by crystallographic analysis. This present strategy provides an efficient synthetic method for the design and synthesis of structural isomers based on pyrene-imidazole. |
| Keyword | one-pot reaction pyrene-imidazole structural isomer molecular symmetry crystal structure |
| DOI | 10.3390/molecules24122293 |
| WOS Keyword | ISOMERICALLY PURE ; HIGHLY EFFICIENT ; DEEP-BLUE ; FLUORESCENCE ; PERFORMANCE ; DERIVATIVES ; CRYSTAL ; PACKING ; CONFORMATION |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | Natural Science Foundation of Heilongjiang Province[LH2019B002] ; Postdoctoral Science Foundation of Heilongjiang Province[LBH-Z17014] ; CAS Key Laboratory of Renewable Energy[Y907k71001] |
| WOS Research Area | Biochemistry & Molecular Biology ; Chemistry |
| Funding Organization | Natural Science Foundation of Heilongjiang Province ; Postdoctoral Science Foundation of Heilongjiang Province ; CAS Key Laboratory of Renewable Energy |
| WOS Subject | Biochemistry & Molecular Biology ; Chemistry, Multidisciplinary |
| WOS ID | WOS:000473816900099 |
| Publisher | MDPI |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/25279 |
| Collection | 中国科学院广州能源研究所 |
| Corresponding Author | Fu, Ying |
| Affiliation | 1.Northeast Agr Univ, Coll Sci, Dept Appl Chem, Harbin 150030, Heilongjiang, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 3.Heilongjiang Vocat Coll Biol Sci & Technol, Harbin 150025, Heilongjiang, Peoples R China |
| First Author Affilication | GuangZhou Institute of Energy Conversion,Chinese Academy of Sciences |
| Recommended Citation GB/T 7714 | Liu, Yu-Long,Yang, Liu,Guo, You-Quan,et al. Synthesis and Configurational Character Study of Novel Structural Isomers Based on Pyrene-Imidazole[J]. MOLECULES,2019,24(12):11. |
| APA | Liu, Yu-Long,Yang, Liu,Guo, You-Quan,Xu, Guo-Qiang,Qu, Bin,&Fu, Ying.(2019).Synthesis and Configurational Character Study of Novel Structural Isomers Based on Pyrene-Imidazole.MOLECULES,24(12),11. |
| MLA | Liu, Yu-Long,et al."Synthesis and Configurational Character Study of Novel Structural Isomers Based on Pyrene-Imidazole".MOLECULES 24.12(2019):11. |
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