Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| Hydrodeoxygenation of lignin-derived phenoic compounds to hydrocarbon fuel over supported Ni-based catalysts | |
Zhang, Xinghua1 ; Tang, Wenwu; Zhang, Qi; Wang, Tiejun; Ma, Longlong1
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| 2018-10-01 | |
| Source Publication | APPLIED ENERGY
 |
| ISSN | 0306-2619 |
| Volume | 227Pages:73-79 |
| Corresponding Author | Zhang, Xinghua(zhangxh@ms.giec.ac.cn) ; Ma, Longlong(mall@ms.giec.ac.cn) |
| Abstract | Ni-based catalysts supported on gamma-Al2O3 and SiO2 were prepared by impregnation. Catalyst characterization was performed using XRD, NH3-TPD,H-2-TPR and chemisorption. Effects of supports on catalytic performance were tested using the hydrodeoxygenation (HDO) of phenolic compounds as a model reaction. Experiment result shows that single phenolic compounds can be converted via HDO reaction over Ni/SiO2 and Ni/gamma-Al2O3 catalysts at 300 degrees C. The hydrocarbon yields are in the range of 60-90%. The effect of supports on the reaction mechanism was also explored. It is found that hydrogenation of the aromatic ring preferentially occurs over Ni/SiO2 catalyst while the cleavage of C-AR-O bond preferentially occurs over Ni/gamma-Al2O3 catalyst in the HDO of phenol. Compared to Ni/gamma-Al2O3 catalyst, Ni/SiO2 catalyst exhibits better repeatability and higher catalytic activity for hydrocarbon yield when mixed phenolic compounds were used as feedstock in the HDO reaction, and the carbon deposited on the surface of Ni/SiO2 catalyst is lower. |
| Keyword | Lignin Phenolic compounds Hydrodeoxygenation Ni/SiO2 Hydrocarbon |
| DOI | 10.1016/j.apenergy.2017.08.078 |
| WOS Keyword | BIO-OIL ; BIOMASS ; GUAIACOL ; HYDROGENATION ; DECOMPOSITION ; DEGRADATION ; TEMPERATURE ; CHEMICALS ; GASOLINE ; PT/SIO2 |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | National Natural Science Foundation of China - China[51536009] ; National Natural Science Foundation of China - China[51576198] ; National Key Technology R & D Program - China[2015BAD15B06] ; STS program of Chinese Academy of Sciences - China[KFJ-EW-STS-138] ; Science and Technology Planning Project of Guangdong Province - China[2014A01016020] ; Youth Innovation Promotion Association of Chinese Academy of Sciences - China[2015288] |
| WOS Research Area | Energy & Fuels ; Engineering |
| Funding Organization | National Natural Science Foundation of China - China ; National Key Technology R & D Program - China ; STS program of Chinese Academy of Sciences - China ; Science and Technology Planning Project of Guangdong Province - China ; Youth Innovation Promotion Association of Chinese Academy of Sciences - China |
| WOS Subject | Energy & Fuels ; Engineering, Chemical |
| WOS ID | WOS:000445987200008 |
| Publisher | ELSEVIER SCI LTD |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/24007 |
| Collection | 中国科学院广州能源研究所 |
| Corresponding Author | Zhang, Xinghua; Ma, Longlong |
| Affiliation | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 2.CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 3.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Guangdong, Peoples R China |
| First Author Affilication | GuangZhou Institute of Energy Conversion,Chinese Academy of Sciences |
| Recommended Citation GB/T 7714 | Zhang, Xinghua,Tang, Wenwu,Zhang, Qi,et al. Hydrodeoxygenation of lignin-derived phenoic compounds to hydrocarbon fuel over supported Ni-based catalysts[J]. APPLIED ENERGY,2018,227:73-79. |
| APA | Zhang, Xinghua,Tang, Wenwu,Zhang, Qi,Wang, Tiejun,&Ma, Longlong.(2018).Hydrodeoxygenation of lignin-derived phenoic compounds to hydrocarbon fuel over supported Ni-based catalysts.APPLIED ENERGY,227,73-79. |
| MLA | Zhang, Xinghua,et al."Hydrodeoxygenation of lignin-derived phenoic compounds to hydrocarbon fuel over supported Ni-based catalysts".APPLIED ENERGY 227(2018):73-79. |
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