Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| Catalytic Transfer Hydrogenation of Ethyl Levulinate into gamma-Valerolactone Over Zirconium Oxide Derived from Zirconyl Nitrate | |
Dong, Kaijun1,2,3 ; Zhang, Jun1,2,3; Luo, Weimin1,2,3; Su, Lin1,2,3; Huang, Zhilin1,2,3,4
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| 2017-12-01 | |
| Source Publication | JOURNAL OF BIOBASED MATERIALS AND BIOENERGY
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| ISSN | 1556-6560 |
| Volume | 11Issue:6Pages:543-552 |
| Corresponding Author | Zhang, Jun(zhangjun@ms.giec.ac.cn) |
| Abstract | A series of zirconium based catalysts were synthesized to study the transfer hydrogenation of biomass derived ethyl levulinate into gamma-valerolactone (GVL) using lower alcohols as hydrogen donors. The essential textural and chemical characteristics of prepared samples were identified by various techniques including SEM, XRD, NH3-TPD, TGA, CO2-TPD and nitrogen physisorption. Parameters such as hydrogen donor, catalyst type, temperature, stirring rate, and catalyst dosage were found to play a critical role in GVL production. A promising GVL yield of 98.3 mol% with a highest GVL formation rate at 5239.4 mu mol g(cat)(-1) h(-1) was obtained in isopropanol at 433 K over zirconium oxide derived from zirconyl nitrate. The recycling experiments revealed that the zirconium oxide catalyst derived from zirconyl nitrate presented relatively satisfied performance and stability. |
| Keyword | gamma-Valerolactone Hydrogen Donors Zirconium Oxide Zirconyl Nitrate |
| DOI | 10.1166/jbmb.2017.1717 |
| WOS Keyword | MEERWEIN-PONNDORF-VERLEY ; BIOMASS ; CONVERSION ; ACID ; EFFICIENT ; ESTERS ; REDUCTIONS |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | Natural Science Foundation of Guangdong Province, China[2014A030310386] ; Natural Science Foundation of Guangdong Province, China[2016A030313173] ; Natural Science Foundation of Guangdong Province, China[2015A030310408] ; Science and Technology Planning Project of Guangdong Province, China[2015A040404039] ; Science and Technology Planning Project of Guangdong Province, China[2015B 090901012] |
| WOS Research Area | Chemistry ; Energy & Fuels ; Materials Science |
| Funding Organization | Natural Science Foundation of Guangdong Province, China ; Science and Technology Planning Project of Guangdong Province, China |
| WOS Subject | Chemistry, Applied ; Energy & Fuels ; Materials Science, Biomaterials |
| WOS ID | WOS:000430408000002 |
| Publisher | AMER SCIENTIFIC PUBLISHERS |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/23181 |
| Collection | 中国科学院广州能源研究所 |
| Corresponding Author | Zhang, Jun |
| Affiliation | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 2.CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 3.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Guangdong, Peoples R China 4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| First Author Affilication | GuangZhou Institute of Energy Conversion,Chinese Academy of Sciences |
| Recommended Citation GB/T 7714 | Dong, Kaijun,Zhang, Jun,Luo, Weimin,et al. Catalytic Transfer Hydrogenation of Ethyl Levulinate into gamma-Valerolactone Over Zirconium Oxide Derived from Zirconyl Nitrate[J]. JOURNAL OF BIOBASED MATERIALS AND BIOENERGY,2017,11(6):543-552. |
| APA | Dong, Kaijun,Zhang, Jun,Luo, Weimin,Su, Lin,&Huang, Zhilin.(2017).Catalytic Transfer Hydrogenation of Ethyl Levulinate into gamma-Valerolactone Over Zirconium Oxide Derived from Zirconyl Nitrate.JOURNAL OF BIOBASED MATERIALS AND BIOENERGY,11(6),543-552. |
| MLA | Dong, Kaijun,et al."Catalytic Transfer Hydrogenation of Ethyl Levulinate into gamma-Valerolactone Over Zirconium Oxide Derived from Zirconyl Nitrate".JOURNAL OF BIOBASED MATERIALS AND BIOENERGY 11.6(2017):543-552. |
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