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Synthesis of CoNi nanowires by heterogeneous nucleation in polyol
Liu, Qiying1,2; Guo, Xiaohui1; Wang, Tiejun2; Li, Yong1; Shen, Wenjie1
2010-06-15
Source PublicationMATERIALS LETTERS
ISSN0167-577X
Volume64Issue:11Pages:1271-1274
Contribution Rank[Liu, Qiying; Guo, Xiaohui; Li, Yong; Shen, Wenjie] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China; [Liu, Qiying; Wang, Tiejun] Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy & Gas Hydrate, Guangzhou 510640, Guangdong, Peoples R China
Corresponding Authorshen98@dicp.ac.cn
AbstractCoNi nanorwires/nanorods, depending on the loading of Ni, were prepared by heterogeneous nucleation in polyol. CoNi nanowires with the length up to 1000 nm and the diameter of about 10 nm were obtained when the loading of Ni was no more than 30%, whereas nanorods with the length of about 500 nm and the diameter of 20 nm were produced with further increasing the loading of Ni. It was revealed that the nanowires might be a core-shell structure where the core was formed by the fast reduction of Co(2+) and the shell was constructed by the combined reduction of Co(2+) and When used for hydrogenolysis of glycerol, the CoNi nanowires showed significantly enhanced glycerol conversion and propanediol selectivity as compared to the pure Co nanowires. (C) 2010 Elsevier B.V. All rights reserved.
SubtypeArticle
Other AbstractCoNi nanorwires/nanorods, depending on the loading of Ni, were prepared by heterogeneous nucleation in polyol. CoNi nanowires with the length up to 1000 nm and the diameter of about 10 nm were obtained when the loading of Ni was no more than 30%, whereas nanorods with the length of about 500 nm and the diameter of 20 nm were produced with further increasing the loading of Ni. It was revealed that the nanowires might be a core-shell structure where the core was formed by the fast reduction of Co(2+) and the shell was constructed by the combined reduction of Co(2+) and When used for hydrogenolysis of glycerol, the CoNi nanowires showed significantly enhanced glycerol conversion and propanediol selectivity as compared to the pure Co nanowires.
KeywordMetallic Alloys Coni Nanowires Crystal Growth Core-shell Structure Shape Control
Subject AreaMaterials Science ; Physics
WOS HeadingsScience & Technology ; Technology ; Physical Sciences
DOI10.1016/j.matlet.2010.03.006
WOS Subject ExtendedMaterials Science ; Physics
URL查看原文
WOS KeywordSURFACE ALLOY ; BIMETALLIC SURFACES ; CHEMICAL-PROPERTIES ; LIQUID POLYOL ; NANOPARTICLES ; NI ; CATALYST ; METHANE ; GROWTH ; COBALT
Indexed BySCI
Language英语
WOS SubjectMaterials Science, Multidisciplinary ; Physics, Applied
WOS IDWOS:000278148900009
Citation statistics
Cited Times:31[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/8496
Collection中国科学院广州能源研究所
生物质化工品制备实验室
Affiliation1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy & Gas Hydrate, Guangzhou 510640, Guangdong, Peoples R China
Recommended Citation
GB/T 7714
Liu, Qiying,Guo, Xiaohui,Wang, Tiejun,et al. Synthesis of CoNi nanowires by heterogeneous nucleation in polyol[J]. MATERIALS LETTERS,2010,64(11):1271-1274.
APA Liu, Qiying,Guo, Xiaohui,Wang, Tiejun,Li, Yong,&Shen, Wenjie.(2010).Synthesis of CoNi nanowires by heterogeneous nucleation in polyol.MATERIALS LETTERS,64(11),1271-1274.
MLA Liu, Qiying,et al."Synthesis of CoNi nanowires by heterogeneous nucleation in polyol".MATERIALS LETTERS 64.11(2010):1271-1274.
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