Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| Recent advances in selective catalytic hydrogenation of nitriles to primary amines | |
Lu, Qiqi1,2; Liu, Jianguo3; Ma, Longlong2,3
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| 2021-12-01 | |
| Source Publication | JOURNAL OF CATALYSIS
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| ISSN | 0021-9517 |
| Volume | 404Pages:475-492 |
| Corresponding Author | Liu, Jianguo(liujg@ms.giec.ac.cn) ; Ma, Longlong(mall@ms.giec.ac.cn) |
| Abstract | Hydrogenation of nitriles into primary amines is a crucial chemical reaction due to the importance of pri-mary amines in the plastic, pharmaceutical, and agrochemical industry. However, the control of the selec-tivity during the reaction is a major issue, which is greatly affected by the used catalysts. Therefore, to show the existing arts and trends of catalytic systems, progress made for the selective catalytic hydro-genation of nitriles into primary amines and the reaction parameters on benzonitrile of each catalytic sys-tem in the last decade are reviewed. This review also briefly discusses the effect of different substrate structures on the selectivity and the substrate scope of each catalytic system, especially the nitriles con-taining functional groups and aliphatic nitriles, which aren't mentioned in the previous reported reviews. The best results for the various chemoselectivity problems are compiled and evaluated. This review aims to critically assess the development, performance, and versatility of various catalytic systems, as well as provide new perspectives to design and apply catalysts on conditions variables and substrate structures. (c) 2021 Elsevier Inc. All rights reserved. |
| Keyword | Nitriles Primary amines Selective hydrogenation Catalytic systems Functional groups |
| DOI | 10.1016/j.jcat.2021.10.028 |
| WOS Keyword | ALKYL-ARYL KETONES ; CARBON-DIOXIDE ; REDUCTIVE AMINATION ; EFFICIENT HYDROGENATION ; AMMONIA BORANE ; COBALT NANOPARTICLES ; GENERAL-SYNTHESIS ; RUTHENIUM ; BENZONITRILE ; WATER |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | National Key R&D Program of China[2018YFB1501500] ; National Natural Science Foundation of China[51976225] |
| WOS Research Area | Chemistry ; Engineering |
| Funding Organization | National Key R&D Program of China ; National Natural Science Foundation of China |
| WOS Subject | Chemistry, Physical ; Engineering, Chemical |
| WOS ID | WOS:000720356400014 |
| Publisher | ACADEMIC PRESS INC ELSEVIER SCIENCE |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/35256 |
| Collection | 中国科学院广州能源研究所 |
| Corresponding Author | Liu, Jianguo; Ma, Longlong |
| Affiliation | 1.Guangzhou Inst Energy Convers, Chinese Acad Sci, Guangdong Prov Key Lab New & Renewable Energy Res, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Southeast Univ, Sch Energy & Environm, Key Lab Energy Thermal Convers & Control, Minist Educ, Nanjing 210096, Jiangsu, Peoples R China |
| Recommended Citation GB/T 7714 | Lu, Qiqi,Liu, Jianguo,Ma, Longlong. Recent advances in selective catalytic hydrogenation of nitriles to primary amines[J]. JOURNAL OF CATALYSIS,2021,404:475-492. |
| APA | Lu, Qiqi,Liu, Jianguo,&Ma, Longlong.(2021).Recent advances in selective catalytic hydrogenation of nitriles to primary amines.JOURNAL OF CATALYSIS,404,475-492. |
| MLA | Lu, Qiqi,et al."Recent advances in selective catalytic hydrogenation of nitriles to primary amines".JOURNAL OF CATALYSIS 404(2021):475-492. |
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