Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| A review on recent developments in N-methylation using CO2 | |
Lin, Shanshan1,2; Liu, Jianguo3; Ma, Longlong1,3
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| 2021-12-01 | |
| Source Publication | JOURNAL OF CO2 UTILIZATION
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| ISSN | 2212-9820 |
| Volume | 54Pages:18 |
| Corresponding Author | Liu, Jianguo(liujg@ms.giec.ac.cn) ; Ma, Longlong(mall@ms.giec.ac.cn) |
| Abstract | Owing to the increasing emissions of carbon dioxide (CO2) in recent years, people's interest in the use of CO2, especially the synthesis of value-added chemicals with CO2 as a C1 blocking, has also increased year by year. In particular, the N-methylation reaction of CO2 to synthesize amines has attracted widespread attention. As an important raw material for chemical synthesis, methylation products have a wide range of uses in industry and even in nature. Using CO2 to replace traditional methylation reagents is not only green and environmentally friendly but also reduces costs. To overcome the thermodynamic and kinetic stability of CO2 and improve the selectivity and conversion rate of the N-methylation reaction, researchers are committed to the development of high-efficiency catalysts such as noble metal-supported or homogeneous catalysts, non-noble metals such as Cu, Ni, Zn, and some new metal-free catalysts. This paper summarizes and reviews the research progress and applications in the high-efficiency catalyst systems and catalytic reaction process conditions of CO2 and H-2 (or organosilane) and amines to form N-methylamine and N, N-dimethylamine compounds in recent years. It is expected to provide a reference for the development of new processes for the catalytic conversion of CO2 into high value-added chemicals. |
| Keyword | CO2 N-methylation N-methylamine N, N-dimethylamine Catalyst DNA methylation |
| DOI | 10.1016/j.jcou.2021.101759 |
| WOS Keyword | METAL-FREE CATALYST ; CARBON-DIOXIDE ; REDUCTIVE FUNCTIONALIZATION ; IONIC LIQUIDS ; AMINES ; HYDROGENATION ; FORMYLATION ; METHANOL ; HYDROSILANES ; EFFICIENT |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | National Natural Science Foundation of China[51976225] |
| WOS Research Area | Chemistry ; Engineering |
| Funding Organization | National Natural Science Foundation of China |
| WOS Subject | Chemistry, Multidisciplinary ; Engineering, Chemical |
| WOS ID | WOS:000711394500002 |
| Publisher | ELSEVIER SCI LTD |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/35172 |
| Collection | 中国科学院广州能源研究所 |
| Corresponding Author | Liu, Jianguo; Ma, Longlong |
| Affiliation | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Southeast Univ, Sch Energy & Environm, Key Lab Energy Thermal Convers & Control, Minist Educ, Nanjing 210096, Peoples R China |
| First Author Affilication | GuangZhou Institute of Energy Conversion,Chinese Academy of Sciences |
| Recommended Citation GB/T 7714 | Lin, Shanshan,Liu, Jianguo,Ma, Longlong. A review on recent developments in N-methylation using CO2[J]. JOURNAL OF CO2 UTILIZATION,2021,54:18. |
| APA | Lin, Shanshan,Liu, Jianguo,&Ma, Longlong.(2021).A review on recent developments in N-methylation using CO2.JOURNAL OF CO2 UTILIZATION,54,18. |
| MLA | Lin, Shanshan,et al."A review on recent developments in N-methylation using CO2".JOURNAL OF CO2 UTILIZATION 54(2021):18. |
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