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Effect of Torrefaction Pretreatment on Chemical Structure and Pyrolysis Behaviors of Cellulose
Zheng,Anqing1,2,3,4; Li,Luwei2,3,4; Zhao,Zengli2,3,4; Tian,Yuanyu1; Li,Haibin2,3,4
2021
Source PublicationIOP Conference Series: Earth and Environmental Science
ISSN1755-1307
Volume621Issue:1
AbstractAbstract In order to obtain the effect of torrefaction pretreatment on chemical structure and pyrolysis reactivity of cellulose, torrefaction of cellulose was conducted in a fixed bed reactor at varying torrefaction temperature and residence time. The chemical composition and structural alterations of torrefied cellulose were characterized by elemental analyzer and Fourier-transform infrared spectroscopy (FTIR). The investigation on the pyrolysis behaviors of raw and torrefied cellulose were carried out by using a thermogravimetric analyzer (TGA). The results showed that torrefaction of cellulose mainly proceeded a series of deoxygenation, polycondensation and carbonization reactions. The severe carbonization of cellulose occurred when the torrefaction temperature and residence time were larger than 300°C and 40 min, resulting in the drastic decrease in the pyrolysis reactivity of cellulose. Hence, the optimal torrefaction temperature should not exceed 280°C.
DOI10.1088/1755-1315/621/1/012014
Language英语
WOS IDIOP:EES_621_1_012014
PublisherIOP Publishing
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Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/34946
Collection中国科学院广州能源研究所
Affiliation1.State Key Laboratory of Heavy Oil Processing, China University of Petroleum (East China), Qingdao, Shandong 266580, China.
2.Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, PR China.
3.CAS Key Laboratory of Renewable Energy, Guangzhou 510640, PR China.
4.Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development, Guangzhou 510640, PR China.
Recommended Citation
GB/T 7714
Zheng,Anqing,Li,Luwei,Zhao,Zengli,et al. Effect of Torrefaction Pretreatment on Chemical Structure and Pyrolysis Behaviors of Cellulose[J]. IOP Conference Series: Earth and Environmental Science,2021,621(1).
APA Zheng,Anqing,Li,Luwei,Zhao,Zengli,Tian,Yuanyu,&Li,Haibin.(2021).Effect of Torrefaction Pretreatment on Chemical Structure and Pyrolysis Behaviors of Cellulose.IOP Conference Series: Earth and Environmental Science,621(1).
MLA Zheng,Anqing,et al."Effect of Torrefaction Pretreatment on Chemical Structure and Pyrolysis Behaviors of Cellulose".IOP Conference Series: Earth and Environmental Science 621.1(2021).
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