Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| Homogeneous Base-Free Oxidation of 5-Hydroxymethyfufural to 2, 5-Furandicarboxylic Acid over Au/Mg(OH)(2) Catalysts | |
Cai, Chiliu1,2,3 ; Xu, Jiangong4; Wang, Haiyong1,2,3; Xin, Haosheng1,2,3; Zhang, Qi1,2,3; Wang, Chenguang1,2,3; Ma, Longlong1,2,3; Liu, Qiying1,2,3
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| 2020-11-06 | |
| Source Publication | CHEMISTRYSELECT
 |
| ISSN | 2365-6549 |
| Volume | 5Issue:41Pages:12785-12790 |
| Corresponding Author | Liu, Qiying(liugy@ms.giec.ac.cn) |
| Abstract | 2, 5-Furandicarboxylic acid (FDCA) obtained from selective 5-hydroxymethyfufural (HMF) oxidation is an important biodegradable polyester monomer and its production strongly depends on homogeneous base additives. The production of FDCA over solid base catalyst is green and environment-friendly. Herein, Au/Mg(OH)2 as the metal-solid base catalyst, was prepared by a simple colloidal method and applied to the oxidation of HMF. Detailed characterizations (XRD, TEM, XPS, TGA, CO2-TPD, etc.) were performed to uncover the structure-activity relationship of the catalyst. 92.6 % yield of FDCA was achieved under the optimal reaction condition. Moreover, a plausible mechanism for HMF oxidation over the metal-solid base catalyst was proposed by combining the surface properties of catalyst with the oxidation reaction results. |
| Keyword | Au Mg(OH)(2) catalyst 5-hydroxymethyfufural Aerobic oxidation FDCA |
| DOI | 10.1002/slct.202003408 |
| WOS Keyword | FREE AEROBIC OXIDATION ; 2,5-FURANDICARBOXYLIC ACID ; SELECTIVE OXIDATION ; BIOMASS ; CONVERSION ; EFFICIENT ; MG(OH)(2) ; CHEMICALS ; NANORODS ; MGO |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | National Key R&D Program of China[2019YFC1905303] ; Natural Science Foundation of Guangdong Province[2017A030308010] ; National Natural Science Foundation of China[51976220] ; DNL Cooperation Fund, CAS[DNL180302] |
| WOS Research Area | Chemistry |
| Funding Organization | National Key R&D Program of China ; Natural Science Foundation of Guangdong Province ; National Natural Science Foundation of China ; DNL Cooperation Fund, CAS |
| WOS Subject | Chemistry, Multidisciplinary |
| WOS ID | WOS:000586036200019 |
| Publisher | WILEY-V C H VERLAG GMBH |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/34863 |
| Collection | 中国科学院广州能源研究所 |
| Corresponding Author | Liu, Qiying |
| Affiliation | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China 2.Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou 510640, Peoples R China 3.Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou 510640, Peoples R China 4.Xinxiang Med Coll, Affiliated Hosp 3, Xinxiang 453200, Henan, Peoples R China |
| First Author Affilication | GuangZhou Institute of Energy Conversion,Chinese Academy of Sciences |
| Recommended Citation GB/T 7714 | Cai, Chiliu,Xu, Jiangong,Wang, Haiyong,et al. Homogeneous Base-Free Oxidation of 5-Hydroxymethyfufural to 2, 5-Furandicarboxylic Acid over Au/Mg(OH)(2) Catalysts[J]. CHEMISTRYSELECT,2020,5(41):12785-12790. |
| APA | Cai, Chiliu.,Xu, Jiangong.,Wang, Haiyong.,Xin, Haosheng.,Zhang, Qi.,...&Liu, Qiying.(2020).Homogeneous Base-Free Oxidation of 5-Hydroxymethyfufural to 2, 5-Furandicarboxylic Acid over Au/Mg(OH)(2) Catalysts.CHEMISTRYSELECT,5(41),12785-12790. |
| MLA | Cai, Chiliu,et al."Homogeneous Base-Free Oxidation of 5-Hydroxymethyfufural to 2, 5-Furandicarboxylic Acid over Au/Mg(OH)(2) Catalysts".CHEMISTRYSELECT 5.41(2020):12785-12790. |
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