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Development of lithium hydroxide-metal organic framework-derived porous carbon composite materials for efficient low temperature thermal energy storage
Yang, Xiangyu1,3; Li, Shijie2; Zhao, Jianguo1,2; Wang, Xiaomin1; Huang, Hongyu3; Wang, Yongzhen1; Deng, Lisheng3
2021-12-01
Source PublicationMICROPOROUS AND MESOPOROUS MATERIALS
ISSN1387-1811
Volume328Pages:10
Corresponding AuthorZhao, Jianguo(zhaojianguo@sxdtdx.edu.cn) ; Huang, Hongyu(huanghy@ms.giec.ac.cn)
AbstractLithium hydroxide based chemical heat storage (CHS) materials with high energy density and long storage periods have become the limelight of research for efficient use of low-temperature thermal energy and long-term storage. Herein, we report a novel LiOH composite CHS material with a porous carbon material derived from the zeolite imidazolate framework (ZIF-8) as supporting porous carbon matrix (ZSPCM). The Li/ZSPCM composite exhibits remarkable heat storage density up to 1373.3 kJ kg(-1) with low charging temperature and good water adsorption ability owing to the large specific surface area of ZSPCM and well-dispersed small LiOH particles on it, which increase the contact between LiOH and H2O molecules and concomitant improvement in storage performance. In addition, the storage capacity of this composite material has no significantly degradation after 15 cycles of repeated hydration and dehydration, indicating its excellent cycle stability. And the thermal conductivity of Li/ZSPCM composite also shows a significant improvement over pristine LiOH by virtue of the outstanding thermal conductivity of the ZSPCM. This work develops a promising LiOH CHS material may sheds light on future directions for long period storage of low-temperature heat energy and the further exploitation of ZSPCM.
KeywordLiOH CHS materials Remarkable heat storage density Cycle stability Low-temperature heat storage
DOI10.1016/j.micromeso.2021.111455
WOS KeywordHEAT-STORAGE ; HIGHLY EFFICIENT ; ADSORPTION ; ENHANCEMENT ; ZIF-8
Indexed BySCI
Language英语
Funding ProjectNational Natural Science Foundation of China[52071192] ; Key Research Program of Frontier Sciences, CAS[QYZDY-SSW-JSC038] ; Key-Area Research and Development Program of Guangdong Province[2019B11020900]
WOS Research AreaChemistry ; Science & Technology - Other Topics ; Materials Science
Funding OrganizationNational Natural Science Foundation of China ; Key Research Program of Frontier Sciences, CAS ; Key-Area Research and Development Program of Guangdong Province
WOS SubjectChemistry, Applied ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
WOS IDWOS:000703748300001
PublisherELSEVIER
Citation statistics
Cited Times:4[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/34790
Collection中国科学院广州能源研究所
Corresponding AuthorZhao, Jianguo; Huang, Hongyu
Affiliation1.Taiyuan Univ Technol, Sch Mat Sci & Engn, Taiyuan 030024, Peoples R China
2.Shanxi Datong Univ, Inst Carbon Mat Sci, Datong 037009, Peoples R China
3.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China
First Author AffilicationGuangZhou Institute of Energy Conversion,Chinese Academy of Sciences
Recommended Citation
GB/T 7714
Yang, Xiangyu,Li, Shijie,Zhao, Jianguo,et al. Development of lithium hydroxide-metal organic framework-derived porous carbon composite materials for efficient low temperature thermal energy storage[J]. MICROPOROUS AND MESOPOROUS MATERIALS,2021,328:10.
APA Yang, Xiangyu.,Li, Shijie.,Zhao, Jianguo.,Wang, Xiaomin.,Huang, Hongyu.,...&Deng, Lisheng.(2021).Development of lithium hydroxide-metal organic framework-derived porous carbon composite materials for efficient low temperature thermal energy storage.MICROPOROUS AND MESOPOROUS MATERIALS,328,10.
MLA Yang, Xiangyu,et al."Development of lithium hydroxide-metal organic framework-derived porous carbon composite materials for efficient low temperature thermal energy storage".MICROPOROUS AND MESOPOROUS MATERIALS 328(2021):10.
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