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A photocatalytic reaction kinetics model based on electrical double layer theory(Ⅰ) Surface complexation model at TiO_2/water interface
He Mingxing1; Wang Liangyan2; Li Xinjun2; Li Fangbai3; Xu Yuehua2; Huang Cong2
2002
Source PublicationTransactions of Nonferrous Metals Society of China
ISSN1003-6326
Volume12Issue:4Pages:792
AbstractThe kinetics of photocatalysis can be us ually described by Langmiur-Hinshelwood adsorption expression. The adsorption can be greatly influenced by the surface properties of photocatalyst. Triple layer model (TLM) was c hosen to describe the surface adsorption of TiO_2 based on electrical double la ye r (EDL) theory at the TiO_2/water interface. And through the potentiometric titration the parameters of TLM were determined by the extrapolation method and Fiteql3.1 software. The results show that surface complexation dominates the surface charge and the numerical calculation fits the experiment data satisfactorily.
KeywordTi_O2 photocatalysis model adsorption
Language英语
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/34675
Collection中国科学院广州能源研究所
Affiliation1.Panzhihua Institute of Iron and Steel
2.中国科学院广州能源研究所
3.Guangdong Institute of Eco-Environment and Soil Science
Recommended Citation
GB/T 7714
He Mingxing,Wang Liangyan,Li Xinjun,et al. A photocatalytic reaction kinetics model based on electrical double layer theory(Ⅰ) Surface complexation model at TiO_2/water interface[J]. Transactions of Nonferrous Metals Society of China,2002,12(4):792.
APA He Mingxing,Wang Liangyan,Li Xinjun,Li Fangbai,Xu Yuehua,&Huang Cong.(2002).A photocatalytic reaction kinetics model based on electrical double layer theory(Ⅰ) Surface complexation model at TiO_2/water interface.Transactions of Nonferrous Metals Society of China,12(4),792.
MLA He Mingxing,et al."A photocatalytic reaction kinetics model based on electrical double layer theory(Ⅰ) Surface complexation model at TiO_2/water interface".Transactions of Nonferrous Metals Society of China 12.4(2002):792.
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