Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| Homogeneous and heterogeneous catalysts for hydrogenation of CO2 to methanol under mild conditions | |
| Bai, Shao-Tao1; De Smet, Gilles2; Liao, Yuhe1,4; Sun, Ruiyan1; Zhou, Cheng1; Beller, Matthias3; Maes, Bert U. W.2; Sels, Bert F.1 | |
| 2021-04-07 | |
| Source Publication | CHEMICAL SOCIETY REVIEWS
 |
| ISSN | 0306-0012 |
| Volume | 50Issue:7Pages:4259-4298 |
| Corresponding Author | Beller, Matthias(Matthias.Beller@catalysis.de) ; Maes, Bert U. W.(bert.maes@uantwerpen.be) ; Sels, Bert F.(bert.sels@kuleuven.be) |
| Abstract | In the context of a carbon neutral economy, catalytic CO2 hydrogenation to methanol is one crucial technology for CO2 mitigation providing solutions for manufacturing future fuels, chemicals, and materials. However, most of the presently known catalyst systems are used at temperatures over 220 degrees C, which limits the theoretical yield of methanol production due to the exothermic nature of this transformation. In this review, we summarize state-of-the-art catalysts, focusing on the rationales behind, for CO2 hydrogenation to methanol at temperatures lower than 170 degrees C. Both hydrogenation with homogeneous and heterogeneous catalysts is covered. Typically, additives (alcohols, amines or aminoalcohols) are used to transform CO2 into intermediates, which can further be reduced into methanol. In the first part, molecular catalysts are discussed, organized into: (1) monofunctional, (2) M/NH bifunctional, and (3) aromatization-dearomatization bifunctional molecular catalysts. In the second part, heterogeneous catalysts are elaborated, organized into: (1) metal/metal or metal/support, (2) active-site/N or active-site/OH bifunctional heterogeneous catalysts, and (3) cooperation of catalysts and additives in a tandem process via crucial intermediates. Although many insights have been gained in this transformation, in particular for molecular catalysts, the mechanisms in the presence of heterogeneous catalysts remain descriptive and insights unclear. |
| DOI | 10.1039/d0cs01331e |
| WOS Keyword | METAL-LIGAND COOPERATION ; TETRADENTATE BIPYRIDINE LIGANDS ; LOW-TEMPERATURE HYDROGENATION ; CARBON-DIOXIDE ; ASYMMETRIC HYDROGENATION ; CARBOXYLIC-ACIDS ; FORMIC-ACID ; NONCOVALENT INTERACTIONS ; SEQUENTIAL HYDROGENATION ; 5-CO-ORDINATE COMPLEXES |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | Federal Excellence of Science (EoS) call of FWO/FNRS (BIOFACT)[30902231] ; European Research Council (ERC)[NoNaCat 670986] ; KU Leuven ; special research fund BOF UAntwerpen |
| WOS Research Area | Chemistry |
| Funding Organization | Federal Excellence of Science (EoS) call of FWO/FNRS (BIOFACT) ; European Research Council (ERC) ; KU Leuven ; special research fund BOF UAntwerpen |
| WOS Subject | Chemistry, Multidisciplinary |
| WOS ID | WOS:000639924700015 |
| Publisher | ROYAL SOC CHEMISTRY |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/33176 |
| Collection | 中国科学院广州能源研究所 |
| Corresponding Author | Beller, Matthias; Maes, Bert U. W.; Sels, Bert F. |
| Affiliation | 1.Katholieke Univ Leuven, Ctr Sustainable Catalysis & Engn, Celestijnenlaan 200F, B-3001 Heverlee, Belgium 2.Univ Antwerp, Dept Chem, Div Organ Synth, Groenenborgerlaan 171, B-2020 Antwerp, Belgium 3.Leibniz Inst Catalysis, Albert Einstein Str 29a, Rostock, Germany 4.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China |
| Recommended Citation GB/T 7714 | Bai, Shao-Tao,De Smet, Gilles,Liao, Yuhe,et al. Homogeneous and heterogeneous catalysts for hydrogenation of CO2 to methanol under mild conditions[J]. CHEMICAL SOCIETY REVIEWS,2021,50(7):4259-4298. |
| APA | Bai, Shao-Tao.,De Smet, Gilles.,Liao, Yuhe.,Sun, Ruiyan.,Zhou, Cheng.,...&Sels, Bert F..(2021).Homogeneous and heterogeneous catalysts for hydrogenation of CO2 to methanol under mild conditions.CHEMICAL SOCIETY REVIEWS,50(7),4259-4298. |
| MLA | Bai, Shao-Tao,et al."Homogeneous and heterogeneous catalysts for hydrogenation of CO2 to methanol under mild conditions".CHEMICAL SOCIETY REVIEWS 50.7(2021):4259-4298. |
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