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Comparative Analysis of 3D Graphene-LiOH center dot H2O Composites by Modification with Phytic Acid and Ascorbic Acid for Low-Grade Thermal Energy Storages
Li, Lin1,2,3; Li, Shijie4; Zeng, Tao1,3; Deng, Lisheng1,3; Huang, Hongyu1,3; Li, Jun1,3; Kobayshi, Noriyuki5; Liu, Lin1,3; Zhou, You6
2021-04-14
Source PublicationENERGY TECHNOLOGY
ISSN2194-4288
Pages10
Corresponding AuthorZeng, Tao(zengtao@ms.giec.ac.cn) ; Huang, Hongyu(huanghy@ms.giec.ac.cn)
Abstract3D Graphene (3D-GF) modified with different additive concentrations (phytic acid [PA] and ascorbic acid [AA]) is developed and then combined with different LiOH contents by the hydrothermal method to obtain composite materials. It can be found that the addition of PA and AA will not destroy the carbon skeleton structure of 3D-GF. With increasing additive content, the thermal conductivities of modified 3D-GF first increase and reach their maximum values at 8 mg mL(-1). The modified 3D-GF with the highest thermal conductivity is selected to be combined with different LiOH contents. The addition of PA and AA can broaden the charging temperature range from 60-110 to 30-200 degrees C and improve the LiOH hydration rate and heat storage density. Compared with the PA-modified composite, the AA-modified composite shows smaller (about 7.6 nm) and more uniform LiOH.H2O particles (the particles size standard deviation of 3D-GF-AA-LiOH.H2O is 1.1503), a larger specific surface area (119 m(2) g(-1)), higher heat storage density (the highest value of 2763 kJ kg(-1) for LiOH.H2O, which can be about 4.2 times of pure LiOH), and less influenced by the change of LiOH content (the thermal conductivity standard deviation of 3D-GF-AA-LiOH.H2O is 0.123).
Keyword3D graphene ascorbic acid lithium hydroxide monohydrate nanoparticles phytic acid thermochemical storages
DOI10.1002/ente.202001086
Indexed BySCI
Language英语
Funding ProjectKey Research Program of Frontier Sciences, Chinese Academy of Sciences, China[QYZDY-SSW-JSC038] ; Science and Technology project of China Energy Investment Corporation[GJNY-20-121] ; Science Technology Planning Project of Guangdong Province, China[2017A050501046]
WOS Research AreaEnergy & Fuels
Funding OrganizationKey Research Program of Frontier Sciences, Chinese Academy of Sciences, China ; Science and Technology project of China Energy Investment Corporation ; Science Technology Planning Project of Guangdong Province, China
WOS SubjectEnergy & Fuels
WOS IDWOS:000640099000001
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Cited Times:7[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/33001
Collection中国科学院广州能源研究所
Corresponding AuthorZeng, Tao; Huang, Hongyu
Affiliation1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou 510640, Peoples R China
4.Shanxi Datong Univ, Inst Carbon Mat Sci, Datong 037009, Shanxi, Peoples R China
5.Nagoya Univ, Dept Chem Engn, Nagoya, Aichi 4648603, Japan
6.China Energy Investment Corp Ltd, Natl Inst Clean & Low Carbon Energy, Beijing 102211, Peoples R China
First Author AffilicationGuangZhou Institute of Energy Conversion,Chinese Academy of Sciences
Recommended Citation
GB/T 7714
Li, Lin,Li, Shijie,Zeng, Tao,et al. Comparative Analysis of 3D Graphene-LiOH center dot H2O Composites by Modification with Phytic Acid and Ascorbic Acid for Low-Grade Thermal Energy Storages[J]. ENERGY TECHNOLOGY,2021:10.
APA Li, Lin.,Li, Shijie.,Zeng, Tao.,Deng, Lisheng.,Huang, Hongyu.,...&Zhou, You.(2021).Comparative Analysis of 3D Graphene-LiOH center dot H2O Composites by Modification with Phytic Acid and Ascorbic Acid for Low-Grade Thermal Energy Storages.ENERGY TECHNOLOGY,10.
MLA Li, Lin,et al."Comparative Analysis of 3D Graphene-LiOH center dot H2O Composites by Modification with Phytic Acid and Ascorbic Acid for Low-Grade Thermal Energy Storages".ENERGY TECHNOLOGY (2021):10.
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