Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| Synthesis of Jet Fuel Range Cycloalkanes with Cyclopentanone and Furfural | |
Liu, Qiang1,2,3,5; Zhang, Xinghua1,2,3,4 ; Zhang, Qi1,2,3; Liu, Qiying1,2,3; Wang, Chenguang1,2,3; Ma, Longlong1,2,3
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| 2020-06-18 | |
| Source Publication | ENERGY & FUELS
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| ISSN | 0887-0624 |
| Volume | 34Issue:6Pages:7149-7159 |
| Corresponding Author | Zhang, Xinghua(zhangxh@ms.giec.ac.cn) |
| Abstract | In this work, high-density jet fuel range cycloalkanes were synthesized in high yields (similar to 80%) by solvent-free aldol condensation of cyclopentanone and furfural followed by hydrodeoxygenation (HDO). Sodium-promoted magnesium-aluminum mixed oxides (Na-MgAlO) exhibited a high catalytic activity in the aldol condensation of cyclopentanone and furfural under a solvent-free condition. Furfural conversion of 99.4% with almost 100% selectivity for 2-(2-furylmethylidene) cyclopentanone and 2,5-bis(2-furylmethylidene) cyclopentanone were obtained over the 5.7%Na-MgAlO catalyst under mild conditions (80 degrees C, 2 h). The Na-MgAlO catalysts were characterized by multiple technologies, such as N-2 physisorption, powder X-ray diffraction, Fourier transform infrared spectra, and CO2 temperature-programmed desorption, and so on. It was found that the high catalytic activity for aldol condensation of cyclopentanone and furfural was clearly related to the amount and strength of basicity of Na-MgAlO catalysts. Finally, the condensation products were converted to jet fuel range cycloalkanes by HDO over Pd/C and HZSM-5 catalysts. The density, heating value, and freezing point of the HDO liquid products were 0.83 g/cm(3), 43.1 MJ/Kg, and -27.7 degrees C, respectively. The results suggest that these cycloalkanes are promising as blending components for jet fuel. |
| DOI | 10.1021/acs.energyfuels.0c00919 |
| WOS Keyword | LAYERED DOUBLE HYDROXIDES ; SOLVENT-FREE SYNTHESIS ; DENSITY AVIATION FUEL ; SOLID-BASE CATALYST ; MG-AL HYDROTALCITES ; ONE-POT SYNTHESIS ; ALDOL-CONDENSATION ; BRANCHED ALKANES ; GAMMA-VALEROLACTONE ; EFFICIENT SYNTHESIS |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | National Natural Science Foundation of China[51876210] ; National Key Research and Development Project[2017YFE0106600] ; Transformational Technologies for Clean Energy and Demonstration, Strategic Priority Research Program of the Chinese Academy of Sciences[XDA21060102] ; local Innovative and Research Teams Project of Guangdong Pearl River Talents Program[2017BT01N092] ; Tip-top Scientific and Technical Innovative Youth Talents of Guangdong Special Support Program[2019TQ05L238] |
| WOS Research Area | Energy & Fuels ; Engineering |
| Funding Organization | National Natural Science Foundation of China ; National Key Research and Development Project ; Transformational Technologies for Clean Energy and Demonstration, Strategic Priority Research Program of the Chinese Academy of Sciences ; local Innovative and Research Teams Project of Guangdong Pearl River Talents Program ; Tip-top Scientific and Technical Innovative Youth Talents of Guangdong Special Support Program |
| WOS Subject | Energy & Fuels ; Engineering, Chemical |
| WOS ID | WOS:000552662200050 |
| Publisher | AMER CHEMICAL SOC |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/27524 |
| Collection | 中国科学院广州能源研究所 |
| Corresponding Author | Zhang, Xinghua |
| Affiliation | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China 2.CAS Key Lab Renewable Energy, Guangzhou 510640, Peoples R China 3.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China 4.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 5.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| First Author Affilication | GuangZhou Institute of Energy Conversion,Chinese Academy of Sciences |
| Recommended Citation GB/T 7714 | Liu, Qiang,Zhang, Xinghua,Zhang, Qi,et al. Synthesis of Jet Fuel Range Cycloalkanes with Cyclopentanone and Furfural[J]. ENERGY & FUELS,2020,34(6):7149-7159. |
| APA | Liu, Qiang,Zhang, Xinghua,Zhang, Qi,Liu, Qiying,Wang, Chenguang,&Ma, Longlong.(2020).Synthesis of Jet Fuel Range Cycloalkanes with Cyclopentanone and Furfural.ENERGY & FUELS,34(6),7149-7159. |
| MLA | Liu, Qiang,et al."Synthesis of Jet Fuel Range Cycloalkanes with Cyclopentanone and Furfural".ENERGY & FUELS 34.6(2020):7149-7159. |
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