Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| One-pot hydrodeoxygenation of biomass furan derivatives into decane under mild conditions over Pd/C combined with phosphotungstic acid | |
Li, Song1,2,3,4; Yan, Long1,2,3; Liu, Qiying1,2,3 ; Liu, Jianguo1,2,3; Liu, Qiyu5; Fan, Wei5; Zhao, Xuelai6; Zhang, Xinghua1,2,3; Wang, Chenguang1,2,3; Ma, Longlong1,2,3; Zhang, Qi1,2,3
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| 2020-05-07 | |
| Source Publication | GREEN CHEMISTRY
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| ISSN | 1463-9262 |
| Volume | 22Issue:9Pages:2889-2900 |
| Corresponding Author | Yan, Long(yanlong@ms.giec.ac.cn) ; Zhang, Qi(zhangqi@ms.giec.ac.cn) |
| Abstract | One-pot hydrodeoxygenation (HDO) of biomass furan derivatives into long-chain alkanes remains unclear owing to the complicated reactions at high temperatures. Here, Pd/C combined with phosphotungstic acid (HPW), a strong Bronsted solid acid promoter, was developed to produce decane under mild conditions through the one-pot HDO of delta-furfurylidenelevulinic acid (FDLA). A 93.16% sum yield of alkanes including 89.53% yield of decane was obtained under 3 MPa H-2 at 170 degrees C for 4 h. The ring-opening and HDO of furans are accomplished at preheating stage, which enable to clarify the complicated reaction pathway. In addition, experimental validations and catalytic characterizations confirm that the synergistic effect of active acid-metal sites plays a critical role in the generation of alkanes via the formation and hydrogenolysis of lactone intermediates to aldehyde/alcohol. This work provides guidance for the one-pot HDO of biomass furan derivatives via the combination of metal catalyst and strong Bronsted solid acid under mild conditions. |
| DOI | 10.1039/d0gc00428f |
| WOS Keyword | FUEL RANGE ALKANES ; LEVULINIC ACID ; HETEROPOLY ACID ; BIFUNCTIONAL CATALYSTS ; LIQUID ALKANES ; CONVERSION ; CELLULOSE ; PLATFORM ; DIESEL ; DEOXYGENATION |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | National Key R&D Program of China[2017YFE0106600] ; National Natural Science Foundation of China[51876209] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDA21060102] ; Natural Science Foundation of Guangdong Province[2017A030308010] |
| WOS Research Area | Chemistry ; Science & Technology - Other Topics |
| Funding Organization | National Key R&D Program of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Natural Science Foundation of Guangdong Province |
| WOS Subject | Chemistry, Multidisciplinary ; Green & Sustainable Science & Technology |
| WOS ID | WOS:000533979200022 |
| Publisher | ROYAL SOC CHEMISTRY |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/27135 |
| Collection | 中国科学院广州能源研究所 |
| Corresponding Author | Yan, Long; Zhang, Qi |
| Affiliation | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China 2.CAS Key Lab Renewable Energy, Guangzhou 510640, Peoples R China 3.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China 4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 5.Univ Massachusetts, Dept Chem Engn, 159 Goessman Lab,686 N Pleasant St, Amherst, MA 01003 USA 6.Univ Sci & Technol China, Dept Thermal Sci & Energy Engn, Hefei 233022, Peoples R China |
| First Author Affilication | GuangZhou Institute of Energy Conversion,Chinese Academy of Sciences |
| Recommended Citation GB/T 7714 | Li, Song,Yan, Long,Liu, Qiying,et al. One-pot hydrodeoxygenation of biomass furan derivatives into decane under mild conditions over Pd/C combined with phosphotungstic acid[J]. GREEN CHEMISTRY,2020,22(9):2889-2900. |
| APA | Li, Song.,Yan, Long.,Liu, Qiying.,Liu, Jianguo.,Liu, Qiyu.,...&Zhang, Qi.(2020).One-pot hydrodeoxygenation of biomass furan derivatives into decane under mild conditions over Pd/C combined with phosphotungstic acid.GREEN CHEMISTRY,22(9),2889-2900. |
| MLA | Li, Song,et al."One-pot hydrodeoxygenation of biomass furan derivatives into decane under mild conditions over Pd/C combined with phosphotungstic acid".GREEN CHEMISTRY 22.9(2020):2889-2900. |
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