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Effects of the joint application of phosphate rock, ferric nitrate and plant ash on the immobility of As, Pb and Cd in soils
Li, Qiqi1; Zhong, Huiqiong2; Cao, Yan1,2,3,4
2020-07-01
Source PublicationJOURNAL OF ENVIRONMENTAL MANAGEMENT
ISSN0301-4797
Volume265Pages:7
Corresponding AuthorCao, Yan(caoyan@ms.giec.ac.cn)
AbstractPhosphate rock (PR) and ferric salts have been frequently used to immobilize heavy metal(loid)s in soils, but in varied efficiencies referring to different metal(loid) pollutants. This study explored the effective application of plant ash (PA) to the previous formula of phosphate rock (PR) and ferric salts (Fe(NO3)(3)) (PR + Fe3++PA), compared to only PR, on the bioavailability and immobility of multi-metal(loid)s of selected arsenic (As), lead (Pb) and cadmium (Cd) in soils. Results from NaHCO3-extraction and toxicity characteristic leaching procedure (TCLP) implied the increase of the As mobility in soils by 7.0% and 2.6% using PR only, but the significant reduction of the As mobility by 24.2% and 82.4% jointly using PR + Fe3++PA. Meanwhile, the application of either PR alone or PR + Fe3++PA in soil significantly decreased Pb and Cd extracting in diethylene triamine pentacetate acid (DTPA) and TCLP, particularly, the immobilization effect of PR + Fe3+ +PA was better than that of PR. The leaching column test further confirmed the high durability of PR + Fe3++PA on the immobilization of As and Pb under the continuous acid exposure, but likely slightly increased the mobility of Cd (the accumulated concentration of Cd, 5.88 mu g/L) compared to that (3.16 mu g/L) in the untreated column (UN-column), which were both much lower than the level V (100 mu g/L) of the Chinese National Quality Standard for Surface Water (GB 3838-2002). Therefore, PR + Fe3++PA exhibited the significant enhancement on the immobilization of As, Pb and Cd under simulated acid rain (SAR) leaching.
KeywordMulti-metal(loid)s contaminations Immobility Phosphate rock Ferric nitrate Grass ash SAR leaching
DOI10.1016/j.jenvman.2020.110576
WOS KeywordCONTAMINATED SOILS ; ARSENIC UPTAKE ; CADMIUM ; ADSORPTION ; MOBILITY ; METALS ; LEAD ; CU ; HYPERACCUMULATOR ; STABILIZATION
Indexed BySCI
Language英语
Funding ProjectNational Natural Science Foundation of China[21676001] ; National Key Research and Development program of China-Intergovernmental International Scientific and Technological Innovation Cooperation[2017YFE0105500]
WOS Research AreaEnvironmental Sciences & Ecology
Funding OrganizationNational Natural Science Foundation of China ; National Key Research and Development program of China-Intergovernmental International Scientific and Technological Innovation Cooperation
WOS SubjectEnvironmental Sciences
WOS IDWOS:000533526800019
PublisherACADEMIC PRESS LTD- ELSEVIER SCIENCE LTD
Citation statistics
Cited Times:8[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/27126
Collection中国科学院广州能源研究所
Corresponding AuthorCao, Yan
Affiliation1.Anhui Univ, Coll Chem & Chem Engn, Hefei 230601, Peoples R China
2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China
3.CAS Key Lab Renewable Energy, Guangzhou 510640, Peoples R China
4.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China
Recommended Citation
GB/T 7714
Li, Qiqi,Zhong, Huiqiong,Cao, Yan. Effects of the joint application of phosphate rock, ferric nitrate and plant ash on the immobility of As, Pb and Cd in soils[J]. JOURNAL OF ENVIRONMENTAL MANAGEMENT,2020,265:7.
APA Li, Qiqi,Zhong, Huiqiong,&Cao, Yan.(2020).Effects of the joint application of phosphate rock, ferric nitrate and plant ash on the immobility of As, Pb and Cd in soils.JOURNAL OF ENVIRONMENTAL MANAGEMENT,265,7.
MLA Li, Qiqi,et al."Effects of the joint application of phosphate rock, ferric nitrate and plant ash on the immobility of As, Pb and Cd in soils".JOURNAL OF ENVIRONMENTAL MANAGEMENT 265(2020):7.
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