Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| Biodiesel continuous esterification process experimental study and equipment design | |
Li, Huiwen1,2,3 ; Lv, Pengmei1,2,3,4; Wang, Zhongming1,2,3; Miao, Changlin1,2,3; Yuan, Zhenhong1,2,3
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| 2020-02-27 | |
| Source Publication | BIOMASS CONVERSION AND BIOREFINERY
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| ISSN | 2190-6815 |
| Pages | 8 |
| Corresponding Author | Miao, Changlin(miaocl@ms.giec.ac.cn) |
| Abstract | Biodiesel is a particularly attractive renewable fuel because it can be used in existing engines, it is environmentally friendly and it is readily synthesized from animal fats and vegetable oils. Waste oil combined with heterogeneous catalysts offers exciting possibilities for improving the economics of biodiesel synthesis. The effects of methanol influx rate, reaction temperature, catalysis dosage and operation approaches on pre-esterification deacidification of trap grease were studied in a laboratory with solid acid catalysts. The results showed the maximum acid value reduction efficiency (96.73%) was obtained, and the acid value decreased sharply (from 120 to 3.92 mgKOH g(-1)) at a methanol influx rate of 0.825 mL/m in, a reaction temperature of 115 degrees C, a catalysis dosage of 2.5%, and a reaction time of 2 h using 50 g of oil. An acid value of 0.89 mgKOH g(-1) and an esterification rate of 99.26% were obtained. When the operational approach was changed to a methanol influx of 1.32 mL/min (methanol to oil molar ratio 6: 1), a reaction time of 30 min under pressure, the methanol influx rate changed to 0.825 mL/min, and then, coupled methanol recovered and purified immediately at atmospheric pressure. A continuous esterification deacidification equipment that is suitable for factory pretreatment deacidification of biodiesel produced from trap grease with a high acid value was designed according to laboratory experiments. |
| Keyword | Biodiesel Esterification Equipment Design Trap grease |
| DOI | 10.1007/s13399-020-00623-2 |
| WOS Keyword | WASTE COOKING OIL ; CRUDE JATROPHA-CURCAS ; SOLID ACID CATALYSTS ; SEED OIL ; TRANSESTERIFICATION ; OPTIMIZATION |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | Guangdong science project[2015B020241002] ; National Key RD Program[2017YFD0601003] ; National Natural Science Foundation of China (NSFC)[21506217] |
| WOS Research Area | Energy & Fuels ; Engineering |
| Funding Organization | Guangdong science project ; National Key RD Program ; National Natural Science Foundation of China (NSFC) |
| WOS Subject | Energy & Fuels ; Engineering, Chemical |
| WOS ID | WOS:000516967400001 |
| Publisher | SPRINGER HEIDELBERG |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/26666 |
| Collection | 中国科学院广州能源研究所 |
| Corresponding Author | Miao, Changlin |
| Affiliation | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China 2.Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou 510640, Peoples R China 3.Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou 510640, Peoples R China 4.Collaborat Innovat Ctr Biomass Energy, Zhengzhou 450002, Henan, Peoples R China |
| First Author Affilication | GuangZhou Institute of Energy Conversion,Chinese Academy of Sciences |
| Recommended Citation GB/T 7714 | Li, Huiwen,Lv, Pengmei,Wang, Zhongming,et al. Biodiesel continuous esterification process experimental study and equipment design[J]. BIOMASS CONVERSION AND BIOREFINERY,2020:8. |
| APA | Li, Huiwen,Lv, Pengmei,Wang, Zhongming,Miao, Changlin,&Yuan, Zhenhong.(2020).Biodiesel continuous esterification process experimental study and equipment design.BIOMASS CONVERSION AND BIOREFINERY,8. |
| MLA | Li, Huiwen,et al."Biodiesel continuous esterification process experimental study and equipment design".BIOMASS CONVERSION AND BIOREFINERY (2020):8. |
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