Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| One-Pot Hydrogenation of Furfural into Tetrahydrofurfuryl Alcohol under Ambient Conditions over PtNi Alloy Catalyst | |
Wu, Jingcheng1,2,3,4; Zhang, Xinghua1,2,3 ; Chen, Qiang1,2,3,4; Chen, Lungang1,2,3; Liu, Qiying1,2,3; Wang, Chenguang1,2,3; Ma, Longlong1,2,3
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| 2020-02-01 | |
| Source Publication | ENERGY & FUELS
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| ISSN | 0887-0624 |
| Volume | 34Issue:2Pages:2178-2184 |
| Corresponding Author | Wang, Chenguang(wangcg@ms.giec.ac.cn) |
| Abstract | Furfural (FAL), a promising renewable platform compound from biomass, can be totally hydrogenated to an industrially important platform chemical, tetrahydrofurfuryl alcohol (THFA). In this work, a high yield of THFA was obtained by one-pot hydrogenation of FAL over a PtNi catalyst under mild reaction conditions. Small PtNi alloy particles were well distributed on active carbon. The catalysts were characterized by several physical-chemical technologies (transmission electron microscopy, X-ray diffraction, energy-dispersive spectroscopy, and inductively coupled plasma spectroscopy). Temperature-programmed reduction with hydrogen and in situ X-ray photoelectron spectroscopy demonstrate the presence of PtNi alloy. The electron-rich metal Pt could facilitate the heterolytic dissociation of hydrogen and promote the hydrogenation of FAL. Pt sites on the surface facilitate the adsorption at aldehyde (C=O) groups, and the furan ring strongly adsorbs on the Ni surface. Low reaction temperature is advantageous to reduce side reactions. Various metal concentrations were employed in this reaction; Pt(3)Ni(3)/C catalyst exhibits the best performance, achieving 99% FAL conversion and 93% THFA yield at 35 degrees C and under 2 MPa H-2. |
| DOI | 10.1021/acs.energyfuels.9b02811 |
| WOS Keyword | SELECTIVE HYDROGENATION ; PHASE HYDROGENATION ; CONVERSION ; BIOMASS ; REACTIVITY ; CELLULOSE ; ACID |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | National Key R&D Program of China[2018YFB1501504] ; National Natural Science Foundation of China[51476175] ; National Natural Science Foundation of China[51536009] ; Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program[2017BTO1N092] ; CAS Pioneer Hundred Talents Plan |
| WOS Research Area | Energy & Fuels ; Engineering |
| Funding Organization | National Key R&D Program of China ; National Natural Science Foundation of China ; Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program ; CAS Pioneer Hundred Talents Plan |
| WOS Subject | Energy & Fuels ; Engineering, Chemical |
| WOS ID | WOS:000518215400108 |
| Publisher | AMER CHEMICAL SOC |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/26622 |
| Collection | 中国科学院广州能源研究所 |
| Corresponding Author | Wang, Chenguang |
| Affiliation | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 51640, Peoples R China 2.Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou 51640, Peoples R China 3.Chinese Acad Sci, Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 51640, Peoples R China 4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| First Author Affilication | GuangZhou Institute of Energy Conversion,Chinese Academy of Sciences |
| Recommended Citation GB/T 7714 | Wu, Jingcheng,Zhang, Xinghua,Chen, Qiang,et al. One-Pot Hydrogenation of Furfural into Tetrahydrofurfuryl Alcohol under Ambient Conditions over PtNi Alloy Catalyst[J]. ENERGY & FUELS,2020,34(2):2178-2184. |
| APA | Wu, Jingcheng.,Zhang, Xinghua.,Chen, Qiang.,Chen, Lungang.,Liu, Qiying.,...&Ma, Longlong.(2020).One-Pot Hydrogenation of Furfural into Tetrahydrofurfuryl Alcohol under Ambient Conditions over PtNi Alloy Catalyst.ENERGY & FUELS,34(2),2178-2184. |
| MLA | Wu, Jingcheng,et al."One-Pot Hydrogenation of Furfural into Tetrahydrofurfuryl Alcohol under Ambient Conditions over PtNi Alloy Catalyst".ENERGY & FUELS 34.2(2020):2178-2184. |
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