Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
Influence of TiO2 crystallinity on TiO2 nanotube confined CdS nanoparticles for photocatalytic hydrogen production | |
Peng, Quanming1,2; Peng, Guiming3; Wu, Liangpeng1,2; Wang, Xiaoyang1,2; Wang, Nan1,2; Li, Xinjun1,2 | |
2020-02-01 | |
Source Publication | INORGANIC AND NANO-METAL CHEMISTRY |
ISSN | 2470-1556 |
Pages | 7 |
Corresponding Author | Li, Xinjun(lixj@ms.giec.ac.cn) |
Abstract | Crystallinity is recognized as an important parameter that influences the photocatalytic performance, meanwhile the confinement effect of TiO2 nanotube is efficient to improve the activity. But how TiO2 crystallinity affects the property of TiO2 nanotube-based catalysts remains unclear. Here, CdS nanoparticles inside of various temperature treated TiO2 nanotube (CdS-in-TiO2NT) was obtained. With the increase of calcination temperature from 300 to 500 degrees C, the crystallinity of TiO2 nanotube is increased resulting in the enhanced hydrogen evolution property of CdS-in-TiO2NT. When the calcination temperature is higher than 500 degrees C, TiO2 nanotube is gradually collapsed, which leads to the decrease of photocatalytic performance of CdS-in-TiO2NT. Further photoluminescence measurements confirm that CdS-in-TiO2NT-500 has most quenched PL emission, which is in accordance with the H-2 production efficiency. The highest hydrogen production rate of CdS-in-TiO2NT-500 is ascribed to the efficient confinement effect, good crystallinity of TiO2 nanotube, and accelerated charge separation efficiency. |
Keyword | TiO2 nanotube CdS crystallinity confinement effect hydrogen production |
DOI | 10.1080/24701556.2020.1723024 |
WOS Keyword | CARBON NANOTUBES ; CALCINATION TEMPERATURE ; WATER ; SUPPORT ; IRON ; H-2 ; MICROSTRUCTURE ; PERFORMANCE ; CATALYST ; CU |
Indexed By | SCI |
Language | 英语 |
Funding Project | Science and Technology Program of Guangzhou, China[201803030019] ; Science and Technology Plan Project of Guangdong Province[2017A050501044] ; National Natural Science Foundation of China[51802305] ; National Natural Science Foundation of China[51802043] ; Analytical & Testing Center, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, China |
WOS Research Area | Chemistry ; Science & Technology - Other Topics |
Funding Organization | Science and Technology Program of Guangzhou, China ; Science and Technology Plan Project of Guangdong Province ; National Natural Science Foundation of China ; Analytical & Testing Center, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, China |
WOS Subject | Chemistry, Inorganic & Nuclear ; Nanoscience & Nanotechnology |
WOS ID | WOS:000512900600001 |
Publisher | TAYLOR & FRANCIS INC |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.giec.ac.cn/handle/344007/26382 |
Collection | 中国科学院广州能源研究所 |
Corresponding Author | Li, Xinjun |
Affiliation | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Peoples R China 2.Univ Chinese Acad Sci, Coll Mat Sci & Optoelect Technol, Beijing, Peoples R China 3.Guangdong Univ Technol, Sch Mat & Energy, Guangzhou, Peoples R China |
First Author Affilication | GuangZhou Institute of Energy Conversion,Chinese Academy of Sciences |
Recommended Citation GB/T 7714 | Peng, Quanming,Peng, Guiming,Wu, Liangpeng,et al. Influence of TiO2 crystallinity on TiO2 nanotube confined CdS nanoparticles for photocatalytic hydrogen production[J]. INORGANIC AND NANO-METAL CHEMISTRY,2020:7. |
APA | Peng, Quanming,Peng, Guiming,Wu, Liangpeng,Wang, Xiaoyang,Wang, Nan,&Li, Xinjun.(2020).Influence of TiO2 crystallinity on TiO2 nanotube confined CdS nanoparticles for photocatalytic hydrogen production.INORGANIC AND NANO-METAL CHEMISTRY,7. |
MLA | Peng, Quanming,et al."Influence of TiO2 crystallinity on TiO2 nanotube confined CdS nanoparticles for photocatalytic hydrogen production".INORGANIC AND NANO-METAL CHEMISTRY (2020):7. |
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