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Carbon quantum dots (CQDs) nanofiltration membranes towards efficient biogas slurry valorization
Yang, Wen-Jie1,2,3; Shao, Dan-Dan1,2,3; Zhou, Zhengzhong4; Xia, Qian-Cheng1,2,3; Chen, Jian3; Cao, Xue-Li1,2,3; Zheng, Tao5; Sun, Shi-Peng1,2,3
2020-04-01
Source PublicationCHEMICAL ENGINEERING JOURNAL
ISSN1385-8947
Volume385Pages:11
Corresponding AuthorSun, Shi-Peng(ssp@njtech.edu.cn)
AbstractIn this article, novel nanofiltration (NF) membranes with highly selective surface and fast water and ion transport channels were fabricated for the valorization of biogas slurry. Unlike conventional thin film composite (TFC) membranes, the novel NF membranes compose hydrophilic carbon quantum dots (CQDs) as the interlayer. The carboxyl groups from CQDs react with the polyethyleneimine (PEI), leading to the lower cross-linking degree in the interfacial polymerization layer of NF membranes. Besides, the presence of the hydrophilic CQDs can create fast water and ion transport channels in the NF membranes. The water permeability of membranes is therefore enhanced significantly from 3.6 to 9.7 LMH.bar(-1). The NF membranes were used to concentrate the amino acids from biogas slurry; it achieved rejection rates above 90% towards model amino acids such as lysine, glutamic acid and leucine, due to its highly positive electrical properties, while allowing most of the unwanted salt ions to permeate through. The excellent selectivity between amino acids and salt ions demonstrates the great potential application of the NF membranes in biogas slurry valorization.
KeywordCarbon quantum dots (CQDs) Biogas slurry Amino acids Thin-film composite (TFC) Nanofiltration
DOI10.1016/j.cej.2019.123993
WOS KeywordTHIN-FILM COMPOSITE ; NANOCOMPOSITE MEMBRANES ; OSMOSIS MEMBRANE ; SEPARATION ; SURFACE ; TECHNOLOGIES ; PERFORMANCE ; CHEMISTRY ; PRESSURE ; REMOVAL
Indexed BySCI
Language英语
Funding ProjectNational Natural Science Foundation of China[21878146] ; Jiangsu Provincial Natural Science Fund Outstanding Youth Project[BK20190037] ; Natural Science Foundation of Jiangsu Province[BK20160495] ; Science & Technology Project of Guangdong Province[2016A010105017] ; Science & Technology Project of Guangdong Province[2017B040404009]
WOS Research AreaEngineering
Funding OrganizationNational Natural Science Foundation of China ; Jiangsu Provincial Natural Science Fund Outstanding Youth Project ; Natural Science Foundation of Jiangsu Province ; Science & Technology Project of Guangdong Province
WOS SubjectEngineering, Environmental ; Engineering, Chemical
WOS IDWOS:000507465200034
PublisherELSEVIER SCIENCE SA
Citation statistics
Cited Times:65[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/26323
Collection中国科学院广州能源研究所
Corresponding AuthorSun, Shi-Peng
Affiliation1.Nanjing Tech Univ, State Key Lab Mat Oriented Chem Engn, Nanjing 210009, Peoples R China
2.Nanjing Tech Univ, Jiangsu Natl Synerget Innovat Ctr Adv Mat, Nanjing 210009, Peoples R China
3.Nanjing Tech Univ, Coll Chem Engn, Nanjing 210009, Peoples R China
4.Changzhou Univ, Inst Urban & Rural Min, Changzhou 213164, Peoples R China
5.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China
Recommended Citation
GB/T 7714
Yang, Wen-Jie,Shao, Dan-Dan,Zhou, Zhengzhong,et al. Carbon quantum dots (CQDs) nanofiltration membranes towards efficient biogas slurry valorization[J]. CHEMICAL ENGINEERING JOURNAL,2020,385:11.
APA Yang, Wen-Jie.,Shao, Dan-Dan.,Zhou, Zhengzhong.,Xia, Qian-Cheng.,Chen, Jian.,...&Sun, Shi-Peng.(2020).Carbon quantum dots (CQDs) nanofiltration membranes towards efficient biogas slurry valorization.CHEMICAL ENGINEERING JOURNAL,385,11.
MLA Yang, Wen-Jie,et al."Carbon quantum dots (CQDs) nanofiltration membranes towards efficient biogas slurry valorization".CHEMICAL ENGINEERING JOURNAL 385(2020):11.
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