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Synergistic effect of hydrothermal co-carbonization of sewage sludge with fruit and agricultural wastes on hydrochar fuel quality and combustion behavior
He, Chao1; Zhang, Zhao1; Ge, Chaofeng1; Liu, Wen2; Tang, Yetao1; Zhuang, Xiuzheng3; Qiu, Rongliang1
2019-12-01
Source PublicationWASTE MANAGEMENT
ISSN0956-053X
Volume100Pages:171-181
Corresponding AuthorHe, Chao(hechao25@mail.sysu.edu.cn)
AbstractIn order to improve fuel quality of sewage sludge, fruit and agricultural wastes have been selected for hydrothermal co-carbonization. After hydrothermal co-carbonization, organics retention was facilitated, while O/C and H/C atomic ratios of hydrochars were substantially upgraded. Particularly, hydrochar from hydrothermal co-carbonization of sewage sludge with peanut shells at mass ratio of 1:3 (denoted as "SS: PS = 1:3") showed the highest fuel ratio of 0.79 and its carbon content was increased to 50.0% with significantly decreased O/C and H/C atomic ratios. Furthermore, higher heating value of hydrochars from hydrothermal co-carbonization was increased by nearly 2.65-fold and reached 21.72 MJ/kg. Moreover, the most favorable aromatization occurred when sewage sludge and peanut shells blending ratio was 3:1 or 1:1, whereas hydrothermal co-carbonization induced more -C=O and -OH than -COOH in hydrochars due to synergistic decarboxylation. A relatively higher value of point of zero charge for hydrochars from hydrothermal co-carbonization implied improved hydrophobicity. Combustion kinetics results indicated that hydrothermal co-carbonization balanced activation energies of hydrochars in devolatilizationicombustion stage and char combustion process, rendering a more stable and lasting combustion profile. Hydrochars "SS:PS = 1:3" demonstrated desirable combustion performance. Therefore, hydrothermal co-carbonization can realize sustainable utilization of organic solid wastes towards superior hydrochar solid biofuels. (C) 2019 Elsevier Ltd. All rights reserved.
KeywordBiomass upgrading Synergistic effect Energy recovery Surface functional groups Combustion behavior
DOI10.1016/j.wasman.2019.09.018
WOS KeywordREACTION PATHWAY ; CARBONIZATION ; BIOMASS ; PYROLYSIS ; GASIFICATION ; CONVERSION ; CELLULOSE ; CARBON ; LIQUEFACTION ; TEMPERATURE
Indexed BySCI
Language英语
Funding ProjectNational Key R&D Program of China[2018YFD0800700] ; National Key R&D Program of China[2018YFD0800703] ; Natural Science Foundation of Guangdong Province, China[2018A030313228] ; Guangzhou Municipal Science and Technology Project[201904010342] ; National Natural Science Foundation of China[51906264]
WOS Research AreaEngineering ; Environmental Sciences & Ecology
Funding OrganizationNational Key R&D Program of China ; Natural Science Foundation of Guangdong Province, China ; Guangzhou Municipal Science and Technology Project ; National Natural Science Foundation of China
WOS SubjectEngineering, Environmental ; Environmental Sciences
WOS IDWOS:000494887900019
PublisherPERGAMON-ELSEVIER SCIENCE LTD
Citation statistics
Cited Times:106[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/26094
Collection中国科学院广州能源研究所
Corresponding AuthorHe, Chao
Affiliation1.Sun Yat Sen Univ, Sch Environm Sci & Engn, Guangdong Prov Key Lab Environm Pollut Control &, Guangzhou 510006, Guangdong, Peoples R China
2.Nanyang Technol Univ, Sch Chem & Biomed Engn, 62 Nanyang Dr, Singapore 637459, Singapore
3.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangdong Key Lab New & Renewable Energy Res & De, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
Recommended Citation
GB/T 7714
He, Chao,Zhang, Zhao,Ge, Chaofeng,et al. Synergistic effect of hydrothermal co-carbonization of sewage sludge with fruit and agricultural wastes on hydrochar fuel quality and combustion behavior[J]. WASTE MANAGEMENT,2019,100:171-181.
APA He, Chao.,Zhang, Zhao.,Ge, Chaofeng.,Liu, Wen.,Tang, Yetao.,...&Qiu, Rongliang.(2019).Synergistic effect of hydrothermal co-carbonization of sewage sludge with fruit and agricultural wastes on hydrochar fuel quality and combustion behavior.WASTE MANAGEMENT,100,171-181.
MLA He, Chao,et al."Synergistic effect of hydrothermal co-carbonization of sewage sludge with fruit and agricultural wastes on hydrochar fuel quality and combustion behavior".WASTE MANAGEMENT 100(2019):171-181.
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