Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| Tandem Conversion of Fructose to 2,5-Dimethylfuran with the Aid of Ionic Liquids | |
Zhu, Changhui1,2,3,4; Wang, Haiyong1,2,3,4; Cai, Chilu1,2,3; Bi, Kang6; Cai, Bijuan5; Song, Xiangbo1,2,3,4; Liu, Qiying1,2,3,7 ; Ma, Longlong1,2,3
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| 2019-10-07 | |
| Source Publication | ACS SUSTAINABLE CHEMISTRY & ENGINEERING
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| ISSN | 2168-0485 |
| Volume | 7Issue:19Pages:16026-16040 |
| Corresponding Author | Liu, Qiying(liuqy@ms.giec.ac.cn) |
| Abstract | Biomass-derived 2,5-dimethylfuran (DMF) is an ideal, renewable gasoline additive, and its production with high productivity is highly desirable. A continuous production route was developed to yield DMF from fructose via a tandem strategy, where dehydration catalysts (HY zeolite and niobium phosphate) assisted by 1-butyl-3-methylimidazolium chloride ([BMim] Cl) and hydro-deoxygenation (HDO) catalyst Cu-Ru/C were integrated into one reaction system with gamma-butyrolactone (GBL) as the mobile phase. Optimum conditions, such as temperature, H-2 pressure, weight hourly space velocity, and [BMim]Cl concentration, were investigated systematically, with an initial HDO study by using 5-hydroxymethylfurfural (HMF) as substrate and subsequent tandem dehydration and HDO to produce DMF with fructose as substrate. Among the conditions, the highest yield of DMF at 55.2% was gained by niobium phosphate and Cu-Ru/C, with the aid of [BMim] Cl in a fixed bed. Meanwhile, [BMim]Cl facilitated fructose dehydration to HMF and also mediated HDO of the resultant HMF by stabilization, which was clarified by H-1 NMR and FTIR spectroscopy. Finally, the fact that carbon deposit led to catalyst deactivation was examined thoroughly via a series of characterization techniques. This work achieved continuous DMF production from fructose and laid a foundation for future possible amplification of DMF. |
| Keyword | Fructose [BMim]Cl Dehydration 2,5-Dimethylfuran Hydrodeoxygenation |
| DOI | 10.1021/acssuschemeng.9b02614 |
| WOS Keyword | ONE-POT PRODUCTION ; NIOBIUM PHOSPHATE ; SELECTIVE HYDRODEOXYGENATION ; 5-HYDROXYMETHYLFURFURAL HMF ; LIGNOCELLULOSIC BIOMASS ; EFFICIENT PRODUCTION ; BIPHASIC SOLVENT ; CATALYSTS ; DEHYDRATION ; GLUCOSE |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | National Key R&D Program of China[2018YFB1501402] ; National Science Foundation of China[51576199] ; National Science Foundation of China[51536009] ; Natural Science Foundation of Guangdong Province[2017A030308010] ; DNL Cooperation Fund, CAS[DNL180302] ; Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program[2017BT01N092] |
| WOS Research Area | Chemistry ; Science & Technology - Other Topics ; Engineering |
| Funding Organization | National Key R&D Program of China ; National Science Foundation of China ; Natural Science Foundation of Guangdong Province ; DNL Cooperation Fund, CAS ; Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program |
| WOS Subject | Chemistry, Multidisciplinary ; Green & Sustainable Science & Technology ; Engineering, Chemical |
| WOS ID | WOS:000489986400023 |
| Publisher | AMER CHEMICAL SOC |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/25965 |
| Collection | 中国科学院广州能源研究所 |
| Corresponding Author | Liu, Qiying |
| Affiliation | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 2.Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 3.Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou 510640, Guangdong, Peoples R China 4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 5.South China Agr Univ, Coll Mat & Energy, Guangzhou 510642, Guangdong, Peoples R China 6.Shandong Prov Met Engn Co Ltd, Jinan 250101, Shandong, Peoples R China 7.Univ Chinese Acad Sci, Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China |
| First Author Affilication | GuangZhou Institute of Energy Conversion,Chinese Academy of Sciences |
| Recommended Citation GB/T 7714 | Zhu, Changhui,Wang, Haiyong,Cai, Chilu,et al. Tandem Conversion of Fructose to 2,5-Dimethylfuran with the Aid of Ionic Liquids[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2019,7(19):16026-16040. |
| APA | Zhu, Changhui.,Wang, Haiyong.,Cai, Chilu.,Bi, Kang.,Cai, Bijuan.,...&Ma, Longlong.(2019).Tandem Conversion of Fructose to 2,5-Dimethylfuran with the Aid of Ionic Liquids.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,7(19),16026-16040. |
| MLA | Zhu, Changhui,et al."Tandem Conversion of Fructose to 2,5-Dimethylfuran with the Aid of Ionic Liquids".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 7.19(2019):16026-16040. |
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