Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| In situ synthesis of biomass-derived Ni/C catalyst by self-reduction for the hydrogenation of levulinic acid to gamma-valerolactone | |
Fang, Shuqi1; Cui, Zhibing1,2; Zhu, Yuting2,3; Wang, Chenguang2; Bai, Jing1; Zhang, Xinghua2 ; Xu, Ying2; Liu, Qiying2; Chen, Lungang2; Zhang, Qi2; Ma, Longlong2
| |
| 2019-10-01 | |
| Source Publication | JOURNAL OF ENERGY CHEMISTRY
 |
| ISSN | 2095-4956 |
| Volume | 37Pages:204-214 |
| Corresponding Author | Wang, Chenguang(wangcg@ms.giec.ac.cn) ; Chen, Lungang(chenlg1981@ms.giec.ac.cn) |
| Abstract | Herein, we reported in situ synthesis of biomass-derived Ni/C catalyst by self-reduction with pomelo peel. Compared with the conventional method, which includes carbonization, activation, impregnation and reduction, the entire preparation process was simplified to two steps, which was more straightforward. This synthesis method was green as Ni/C can be prepared without any additional chemical and the self-reduction process was realized in N-2, which can avoid using H-2 thus averting some problems such as storage, transportation and safety of H-2. Meanwhile, the size and dispersion of Ni particles can be controlled by changing carbonization temperature. The synthesis mechanism of Ni/C catalyst with self-reduction was investigated, which was mainly attributed to the carbon and reducing gas produced during the carbonization process. For the catalytic performance of GVL synthesis, a high yield (94.5%) can be obtained and it exhibited good stability up to 5 cycles without obvious loss of catalytic activity. (C) 2019 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved. |
| Keyword | Pomelo peel Ni/C Self-reduction Hydrogenation Levulinic acid gamma-Valerolactone |
| DOI | 10.1016/j.jechem.2019.03.021 |
| WOS Keyword | SELECTIVE HYDROGENATION ; AROMATIC-HYDROCARBONS ; PHENOLIC-COMPOUNDS ; ACTIVATED CARBON ; CONVERSION ; HYDROGENOLYSIS ; LIGNIN ; LIQUID ; SOLVENT |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | National Key R&D Program of China[2018YFB1501504] ; National Natural Science Foundation of China[51776206] ; National Natural Science Foundation of China[21878290] ; Natural Science Foundation of Guangdong province[2017A030313073] ; CAS Pioneer Hundred Talents Program |
| WOS Research Area | Chemistry ; Energy & Fuels ; Engineering |
| Funding Organization | National Key R&D Program of China ; National Natural Science Foundation of China ; Natural Science Foundation of Guangdong province ; CAS Pioneer Hundred Talents Program |
| WOS Subject | Chemistry, Applied ; Chemistry, Physical ; Energy & Fuels ; Engineering, Chemical |
| WOS ID | WOS:000477704000026 |
| Publisher | ELSEVIER |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/25352 |
| Collection | 中国科学院广州能源研究所 |
| Corresponding Author | Wang, Chenguang; Chen, Lungang |
| Affiliation | 1.Zhengzhou Univ, Sch Chem Engn & Energy, Zhengzhou 450001, Henan, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| Recommended Citation GB/T 7714 | Fang, Shuqi,Cui, Zhibing,Zhu, Yuting,et al. In situ synthesis of biomass-derived Ni/C catalyst by self-reduction for the hydrogenation of levulinic acid to gamma-valerolactone[J]. JOURNAL OF ENERGY CHEMISTRY,2019,37:204-214. |
| APA | Fang, Shuqi.,Cui, Zhibing.,Zhu, Yuting.,Wang, Chenguang.,Bai, Jing.,...&Ma, Longlong.(2019).In situ synthesis of biomass-derived Ni/C catalyst by self-reduction for the hydrogenation of levulinic acid to gamma-valerolactone.JOURNAL OF ENERGY CHEMISTRY,37,204-214. |
| MLA | Fang, Shuqi,et al."In situ synthesis of biomass-derived Ni/C catalyst by self-reduction for the hydrogenation of levulinic acid to gamma-valerolactone".JOURNAL OF ENERGY CHEMISTRY 37(2019):204-214. |
| Files in This Item: | There are no files associated with this item. | |||||
Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Edit Comment