Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| Selective hydrogenolysis of 5-hydroxymethylfurfural to 2,5-dimethylfuran over Co3O4 catalyst by controlled reduction | |
Li, Dan2,4; Liu, Qiying1,4 ; Zhu, Changhui1,3,4; Wang, Haiyong1,3,4; Cui, Chunhua1,4; Wang, Chenguang1,4; Ma, Longlong1,4
| |
| 2019-03-01 | |
| Source Publication | JOURNAL OF ENERGY CHEMISTRY
 |
| ISSN | 2095-4956 |
| Volume | 30Pages:34-41 |
| Corresponding Author | Liu, Qiying(liuqy@ms.giec.ac.cn) ; Ma, Longlong(mall@ms.giec.ac.cn) |
| Abstract | 2,5-dimethyfuran (DMF), which is produced from 5-hydroxymethyfurfural (HMF) by hydrodeoxygenation (HDO), is a high quality fuel due to the high heating value, the high octane number and the suitable boiling point. Selective hydrogenation of HMF into liquid fuel DMF has been widely researched. In this paper, Co3O4 catalyst was prepared by co-precipitation and was reduced at different temperatures to form Co-CoOx catalysts. The characterization of catalysts was tested by XRD, TEM, XPS, TPR, BET and NH3-TPD. Co-CoOx possessed a high amount of Co metal and CoOx acidic sites, wherein Co worked as the active hydrogenation sites and CoOx acted as the acid promoter to facilitate the selective HDO of HMF to DMF. The synergistic effect of Co-CoOx is the key for HDO of HMF, obtaining 83.3% of DMF yield at 170 degrees C, 12 h and the reduction temperature of 400 degrees C. This method not only saves the catalyst cost, but also promotes the utilization of biomass energy. (C) 2018 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved. |
| Keyword | HMF DMF Co3O4 catalyst Hydrogenolysis |
| DOI | 10.1016/j.jechem.2018.03.008 |
| WOS Keyword | HIGH-YIELD PRODUCTION ; BIOMASS ; CONVERSION ; FUELS ; HYDRODEOXYGENATION ; TEMPERATURE ; OXIDATION ; FURAN ; TRANSFORMATION ; HYDROGENATION |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | National Natural Science Foundation of China[51576199] ; National Natural Science Foundation of China[51536009] ; Natural Science Fund of Guangdong Province[2017A030308010] |
| WOS Research Area | Chemistry ; Energy & Fuels ; Engineering |
| Funding Organization | National Natural Science Foundation of China ; Natural Science Fund of Guangdong Province |
| WOS Subject | Chemistry, Applied ; Chemistry, Physical ; Energy & Fuels ; Engineering, Chemical |
| WOS ID | WOS:000457878900005 |
| Publisher | ELSEVIER SCIENCE BV |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/25058 |
| Collection | 中国科学院广州能源研究所 |
| Corresponding Author | Liu, Qiying; Ma, Longlong |
| Affiliation | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 2.Univ Sci & Technol China, Nano Sci & Technol Inst, Suzhou 215123, Jiangsu, Peoples R China 3.Univ Chinese Acad Sci, Beijing 101407, Peoples R China 4.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510000, Guangdong, Peoples R China |
| Recommended Citation GB/T 7714 | Li, Dan,Liu, Qiying,Zhu, Changhui,et al. Selective hydrogenolysis of 5-hydroxymethylfurfural to 2,5-dimethylfuran over Co3O4 catalyst by controlled reduction[J]. JOURNAL OF ENERGY CHEMISTRY,2019,30:34-41. |
| APA | Li, Dan.,Liu, Qiying.,Zhu, Changhui.,Wang, Haiyong.,Cui, Chunhua.,...&Ma, Longlong.(2019).Selective hydrogenolysis of 5-hydroxymethylfurfural to 2,5-dimethylfuran over Co3O4 catalyst by controlled reduction.JOURNAL OF ENERGY CHEMISTRY,30,34-41. |
| MLA | Li, Dan,et al."Selective hydrogenolysis of 5-hydroxymethylfurfural to 2,5-dimethylfuran over Co3O4 catalyst by controlled reduction".JOURNAL OF ENERGY CHEMISTRY 30(2019):34-41. |
| Files in This Item: | There are no files associated with this item. | |||||
Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Edit Comment