Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
Transcrystallization of Isotactic Polypropylene/Bacterial Cellulose Hamburger Composite | |
Wang, Bo1,2; Lin, Fu-hua3; Li, Xiang-yang3; Ji, Xu-ran1; Liu, Si-xiao1; Han, Xiao-jing1; Yuan, Zheng-qiu4; Luo, Jun5 | |
2019-03-18 | |
Source Publication | POLYMERS |
Volume | 11Issue:3Pages:9 |
Corresponding Author | Luo, Jun(luoj@gtt.net.cn) |
Abstract | Isotactic polypropylene (iPP) is a commonly used thermoplastic polymer with many excellent properties. But high brittleness, especially at low temperatures, limits the use of iPP. The presence of transcrystallization of iPP makes it possible for fiber-reinforced iPP composites with higher strength. Bacterial cellulose (BC) is a kind of cellulose with great potential to be used as a new filler to reinforce iPP due to its high crystallinity, biodegradability and efficient mechanical properties. In this study, the iPP/BC hamburger composite was prepared by a simple hot press and maleic anhydride grafted polypropylene (MAPP) was used to improve the interface compatibility of iPP and BC. The polarizing microscope (POM) photograph shows that BC successfully induces the transcrystallization of iPP. The differential Scanning Calorimeter (DSC) date proves that the addition of BC could improve the thermal properties and crystallization rate of the composite. Especially, this change is more obvious of the iPP/MAPP/BC. The mechanical properties of the iPP/BC composites were greatly increased. This DSC date is higher than BC; we used BC particles to enhance the iPP in our previous research. The scanning Electron Microscope (SEM) analysis intuitively shows that the interface of the iPP/MAPP/BC is more smooth and flat than the iPP/BC. The fourier Transform infrared spectroscopy (FT-IR) analysis of the iPP/BC hamburger composites was shown that a new C=O group vibration appeared at 1743 cm(-1), which indicated that the hydrogen bond structure of BC molecules was weakened and some hydroxyl groups were substituted after modification which can increase the lipophilicity of BC. These results indicated that the BC fiber can easily induce the transcrystallization of iPP, which has excellent mechanical properties. Moreover, the addition of MAPP contributes greatly to the interface compatibility of iPP and BC. |
Keyword | isotactic polypropylene bacterial cellulose hamburger composite transcrystallization |
DOI | 10.3390/polym11030508 |
WOS Keyword | COPOLYMER |
Indexed By | SCI |
Language | 英语 |
Funding Project | Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi[201802087] ; CAS Key Laboratory of Renewable Energy[Y707k91001] ; doctoral startup project of Taiyuan University of Science and Technology[20162013] |
WOS Research Area | Polymer Science |
Funding Organization | Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi ; CAS Key Laboratory of Renewable Energy ; doctoral startup project of Taiyuan University of Science and Technology |
WOS Subject | Polymer Science |
WOS ID | WOS:000464501400001 |
Publisher | MDPI |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.giec.ac.cn/handle/344007/24826 |
Collection | 中国科学院广州能源研究所 |
Corresponding Author | Luo, Jun |
Affiliation | 1.Taiyuan Univ Sci & Technol, Sch Chem & Biol Engn, Taiyuan 030024, Shanxi, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 3.Shanxi Prov Inst Chem Ind, Taiyuan 030021, Shanxi, Peoples R China 4.Hunan Univ Sci & Technol, Sch Chem & Chem Engn, Xiangtan 411201, Peoples R China 5.Guangzhou Fibre Prod Testing & Res Inst, Guangzhou 510220, Guangdong, Peoples R China |
First Author Affilication | GuangZhou Institute of Energy Conversion,Chinese Academy of Sciences |
Recommended Citation GB/T 7714 | Wang, Bo,Lin, Fu-hua,Li, Xiang-yang,et al. Transcrystallization of Isotactic Polypropylene/Bacterial Cellulose Hamburger Composite[J]. POLYMERS,2019,11(3):9. |
APA | Wang, Bo.,Lin, Fu-hua.,Li, Xiang-yang.,Ji, Xu-ran.,Liu, Si-xiao.,...&Luo, Jun.(2019).Transcrystallization of Isotactic Polypropylene/Bacterial Cellulose Hamburger Composite.POLYMERS,11(3),9. |
MLA | Wang, Bo,et al."Transcrystallization of Isotactic Polypropylene/Bacterial Cellulose Hamburger Composite".POLYMERS 11.3(2019):9. |
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