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Biodiesel production by a highly effective renewable catalyst from pyrolytic rice husk
Zhao, Che1,2,3,4; Yang, Lingmei1,2,3; Xing, Shiyou1,2,3; Luo, Wen1,2,3; Wang, Zhongming1,2,3; Lv, Pengmei1,2,3,5
2018-10-20
Source PublicationJOURNAL OF CLEANER PRODUCTION
ISSN0959-6526
Volume199Pages:772-780
Corresponding AuthorLv, Pengmei(lvpm@ms.giec.ac.cn)
AbstractHigh efficiency and stable CaO-based catalysts which used rice husk biochar as a carrier were utilized to catalyze transesterification of vegetable oil with methanol. The properties of the synthesized catalyst were determined using XRD, TGA, Ff-IR, SEM, EDX, N-2 adsorption/desorption, XPS and the Hammett indicator method. The influences of catalyst preparation, reaction parameters and reusability of catalyst were also investigated. The results indicated that the catalyst activity mainly depended on the pretreatment temperature, structure and basicity of the catalysts. The maximum yield could reach 93.4% under the prepared conditions of 30% CaO loading and 700 degrees C calcination temperature. Meanwhile, after being reused for 10 cycles, there was no noticeable loss of catalyst activity in biodiesel yield (above 85%). The appearance of Ca-O-Si bond on the catalyst surface was the main reason for high stability. The findings suggested that the rice husk biochar based catalyst was a very promising choice for biodiesel production. (C) 2018 Elsevier Ltd. All rights reserved.
KeywordTransesterification Biodiesel CaO-SiO2 Biochar Rice husk
DOI10.1016/j.jclepro.2018.07.242
WOS KeywordSOLID BASE CATALYST ; WASTE COOKING OIL ; PALM OIL ; VEGETABLE-OIL ; SOYBEAN OIL ; HETEROGENEOUS CATALYST ; CALCIUM-OXIDE ; SEWAGE-SLUDGE ; CAO CATALYST ; FLY-ASH
Indexed BySCI
Language英语
Funding ProjectNational Natural Science Foundation of China[51606201] ; National Natural Science Foundation of China[21576260] ; Natural Science Foundation of Guangdong Province[2016A030308004] ; Natural Science Foundation of Guangdong Province[2015A030313720] ; Special Funds of Applied Science and Technology Research of Guangdong Province[2015B020241002]
WOS Research AreaScience & Technology - Other Topics ; Engineering ; Environmental Sciences & Ecology
Funding OrganizationNational Natural Science Foundation of China ; Natural Science Foundation of Guangdong Province ; Special Funds of Applied Science and Technology Research of Guangdong Province
WOS SubjectGREEN & SUSTAINABLE SCIENCE & TECHNOLOGY ; Engineering, Environmental ; Environmental Sciences
WOS IDWOS:000444358400070
PublisherELSEVIER SCI LTD
Citation statistics
Cited Times:93[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/23880
Collection中国科学院广州能源研究所
Corresponding AuthorLv, Pengmei
Affiliation1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China
2.CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
3.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Guangdong, Peoples R China
4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
5.Collaborat Innovat Ctr Biomass Energy, Zhengzhou 450002, Henan, Peoples R China
First Author AffilicationGuangZhou Institute of Energy Conversion,Chinese Academy of Sciences
Recommended Citation
GB/T 7714
Zhao, Che,Yang, Lingmei,Xing, Shiyou,et al. Biodiesel production by a highly effective renewable catalyst from pyrolytic rice husk[J]. JOURNAL OF CLEANER PRODUCTION,2018,199:772-780.
APA Zhao, Che,Yang, Lingmei,Xing, Shiyou,Luo, Wen,Wang, Zhongming,&Lv, Pengmei.(2018).Biodiesel production by a highly effective renewable catalyst from pyrolytic rice husk.JOURNAL OF CLEANER PRODUCTION,199,772-780.
MLA Zhao, Che,et al."Biodiesel production by a highly effective renewable catalyst from pyrolytic rice husk".JOURNAL OF CLEANER PRODUCTION 199(2018):772-780.
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