Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| Conversion of biomass-derived carbohydrates into 5-hydroxymethylfurfural catalyzed by sulfonic acid-functionalized carbon material with high strong-acid density in gamma-valerolactone | |
Huang, Feng1; Li, Wenzhi1; Zhang, Tingwei1; Li, Dawei2; Liu, Qiyu1; Zhu, Xifeng1; Ma, Longlong3
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| 2018-09-01 | |
| Source Publication | RESEARCH ON CHEMICAL INTERMEDIATES
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| ISSN | 0922-6168 |
| Volume | 44Issue:9Pages:5439-5453 |
| Corresponding Author | Li, Wenzhi(liwenzhi@ustc.edu.cn) |
| Abstract | A carbonaceous solid acid catalyst with high strong-acid density was synthesized by facile functionalization of a biomass-derived mesoporous carbon with benzenesulfonic acid. The catalyst was characterized by using Fourier transform infrared spectroscopy, elemental analysis, X-ray photoelectron spectroscopy, transmission electron microscopy, and N-2 adsorption-desorption. The carbonaceous solid catalyst containing Bronsted acid sites was used for the production of 5-hydroxymethylfurfural (HMF) from hexoses such as fructose, glucose, and cellulose in gamma-valerolactone (GVL)-H2O mixture. By reaction at 130 degrees C for 20 min using fructose as a feedstock, an HMF yield 78.1% was achieved. The catalytic performance of the catalyst in conversion of fructose into HMF hardly changed over seven cycles, demonstrating that the catalyst had excellent recyclability. The yields of HMF derived from glucose and cellulose reached 33.2 and 22.5%, respectively, whereas those of total furans were 42.1 and 33.7%, respectively. The proposed reaction system was promising in transforming biomass-based carbohydrates into fine chemicals, given the use of green functionalization methods, the utilization of sustainable biomass-derived carbon precursor and solvents, catalyst with high acid density, and the availability of high HMF yield. |
| Keyword | Carbohydrate Fructose Glucose 5-Hydroxymethylfurfural gamma-Valerolactone Carbon solid acid |
| DOI | 10.1007/s11164-018-3432-y |
| WOS Keyword | IONIC LIQUID ; SELECTIVE CONVERSION ; AQUEOUS-MEDIA ; CORN STALK ; FRUCTOSE ; GLUCOSE ; DEHYDRATION ; HMF ; 5-HMF ; CELLULOSE |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | State Key Program of National Natural Science Foundation of China[51536009] ; Science and Technological Fund of Anhui Province for Outstanding Youth[1508085J01] ; National Key Technology R&D Program of China[2015BAD15B06] |
| WOS Research Area | Chemistry |
| Funding Organization | State Key Program of National Natural Science Foundation of China ; Science and Technological Fund of Anhui Province for Outstanding Youth ; National Key Technology R&D Program of China |
| WOS Subject | Chemistry, Multidisciplinary |
| WOS ID | WOS:000441789200029 |
| Publisher | SPRINGER |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/23770 |
| Collection | 中国科学院广州能源研究所 |
| Corresponding Author | Li, Wenzhi |
| Affiliation | 1.Univ Sci & Technol China, Dept Thermal Sci & Energy Engn, Hefei 230026, Anhui, Peoples R China 2.China Univ Petr East China, State Key Lab Heavy Oil Proc, Qingdao 266580, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China |
| Recommended Citation GB/T 7714 | Huang, Feng,Li, Wenzhi,Zhang, Tingwei,et al. Conversion of biomass-derived carbohydrates into 5-hydroxymethylfurfural catalyzed by sulfonic acid-functionalized carbon material with high strong-acid density in gamma-valerolactone[J]. RESEARCH ON CHEMICAL INTERMEDIATES,2018,44(9):5439-5453. |
| APA | Huang, Feng.,Li, Wenzhi.,Zhang, Tingwei.,Li, Dawei.,Liu, Qiyu.,...&Ma, Longlong.(2018).Conversion of biomass-derived carbohydrates into 5-hydroxymethylfurfural catalyzed by sulfonic acid-functionalized carbon material with high strong-acid density in gamma-valerolactone.RESEARCH ON CHEMICAL INTERMEDIATES,44(9),5439-5453. |
| MLA | Huang, Feng,et al."Conversion of biomass-derived carbohydrates into 5-hydroxymethylfurfural catalyzed by sulfonic acid-functionalized carbon material with high strong-acid density in gamma-valerolactone".RESEARCH ON CHEMICAL INTERMEDIATES 44.9(2018):5439-5453. |
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