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Green nano-encapsulation technique for preparation of phase change nanofibers mats with core-sheath structure
Lu, Yuan1,2; Xiao, Xiudi1; Mo, Jiamei1; Huan, Changmeng1,2; Qi, Shuai1,3; Zhan, Yongjun1; Zhu, Yanqing1; Xu, Gang1,4
2018-10-20
发表期刊COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
ISSN0927-7757
卷号555页码:501-506
通讯作者Xiao, Xiudi(xiaoxd@ms.giec.ac.cn) ; Xu, Gang(xugang@ms.giec.ac.cn)
摘要Inspired by the phase change materials (PCMs) based microcapsules, green phase change nanofibers mats with cores-heath structure based on paraffin wax emulsion (PWE) and polyvinyl alcohol (PVA) for thermal energy storage (TES) is obtained by coaxial electrospinning approach. The PWE could be encapsulated by PVA, simultaneously addressing the leakage issue effectively. In addition, the melting enthalpy (Delta H-m) increased from 3.16 J/g to 48.35 J/g as the core speed rate (R-core) increased from 0.1 to 2.0 it/min, indicating higher R-core can induce higher PWE encapsulation efficiency. Finally, the core-sheath structure PWE@PVA nanofibers mats have high Delta H-m of 48.25 J/g and freezing enthalpy (Delta H-c) of -47.75 J/g. Furthermore, only slightly decreasing tendency on the enthalpy can be observed after 500 heating-cooling cycles, demonstrating good TES stability and practicability of the as-prepared PWE@PVA nanofibers mats. Hence, this study offers new idea for the fabrication method of green PCMs.
关键词Paraffin wax emulsion Coaxial electrospinning Thermal energy storage Phase change materials Nanofibers mats
DOI10.1016/j.colsurfa.2018.07.030
关键词[WOS]THERMAL-ENERGY STORAGE ; HYBRID SHELL ; FABRICATION ; FACILE ; FIBERS
收录类别SCI
语种英语
资助项目National Key R&D Program of China[2018YFD0700200] ; Project of Science and Technology Service Network initiative[KFJ-STS-QYZD-010] ; Major Science and Technology Project of Tibet Autonomous Region[ZD20170017] ; National Natural Science Foundation of China[51506205] ; Youth Innovation Promotion Association CAS[2017400] ; Special Plan of Guangdong Province[2015TQ01N714]
WOS研究方向Chemistry
项目资助者National Key R&D Program of China ; Project of Science and Technology Service Network initiative ; Major Science and Technology Project of Tibet Autonomous Region ; National Natural Science Foundation of China ; Youth Innovation Promotion Association CAS ; Special Plan of Guangdong Province
WOS类目Chemistry, Physical
WOS记录号WOS:000443153100057
出版者ELSEVIER SCIENCE BV
引用统计
被引频次:18[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/23755
专题中国科学院广州能源研究所
通讯作者Xiao, Xiudi; Xu, Gang
作者单位1.Chinese Acad Sci, Guangdong Prov Key Lab New & Renewable Energy Res, Key Lab Renewable Energy, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Univ Sci & Technol China, Nano Sci & Technol Inst, Suzhou 215123, Peoples R China
4.Tibet New Energy Res & Demonstrat Ctr, Lhasa 850000, Tibet, Peoples R China
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GB/T 7714
Lu, Yuan,Xiao, Xiudi,Mo, Jiamei,et al. Green nano-encapsulation technique for preparation of phase change nanofibers mats with core-sheath structure[J]. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,2018,555:501-506.
APA Lu, Yuan.,Xiao, Xiudi.,Mo, Jiamei.,Huan, Changmeng.,Qi, Shuai.,...&Xu, Gang.(2018).Green nano-encapsulation technique for preparation of phase change nanofibers mats with core-sheath structure.COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,555,501-506.
MLA Lu, Yuan,et al."Green nano-encapsulation technique for preparation of phase change nanofibers mats with core-sheath structure".COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS 555(2018):501-506.
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