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Treatment of high arsenic content lead copper matte by a pressure oxidative leaching combined with cyclone and vertical electro-deposition method
Li, Jia-Yuan1; Wang, Tao1; Sun, Zhong-hui1; Wu, Jian-Jian1; Shen, Dian-Ling1; Yuan, Qing3; Li, Xiao-xuan4; Chen, Jun1,2
2018-06-30
Source PublicationSEPARATION AND PURIFICATION TECHNOLOGY
ISSN1383-5866
Volume199Pages:282-288
Corresponding AuthorChen, Jun(cejchen@scut.edu.cn)
AbstractIn this work, pyrite was first used to precipitate arsenic in lead copper matte as the form of FeAsO4 during pressure oxidative leaching process. Initial content of arsenic in lead copper matte is of 7.92 wt%, and concentration of arsenic in leaching liquid can be less than 0.25 g.L-1 when the dosage of pyrite reaches 10 g. Leaching time, liquid-to-solid ratio, oxygen partial pressure, temperature, sulfuric acid concentration, agitation speed, and sodium lignosulfonate content were systematically studied and optimized during pressure oxidative leaching process, and the optimized conditions for pressure oxidative leaching are: leaching time 2 h, liquid-to solid ratio 5:1, oxygen partial pressure 1.2 MPa, temperature 150 degrees C, sulfuric acid 200 g.L-1, agitation speed 500 r.min(-1), sodium lignosulfonate 4 g. A cyclone and vertical electro-deposition method is introduced to treat the above optimized leaching solution. This method is first applied for leaching solution which is obtained from lead copper matte. After having the cyclone and vertical electro-deposition step finished, cathode copper can be greater than 99.00%.
KeywordSeparation Pressure oxidative leaching Lead copper matte Cyclone and vertical electro-deposition
DOI10.1016/j.seppur.2018.01.040
WOS KeywordRECOVERY ; ACID ; SILVER
Indexed BySCI
Language英语
Funding ProjectNational Natural Science Foundation of China[21506065] ; Key Laboratory of Gas Hydrate, Guangzhou Institute of Energy Conversion[Y707ke1001] ; Guangdong Natural Science Foundation[2015A030310472] ; Education Department of Hunan Province[77399] ; Education Department of Hunan Province[17A199] ; Development and application of nonferrous metal functional materials team
WOS Research AreaEngineering
Funding OrganizationNational Natural Science Foundation of China ; Key Laboratory of Gas Hydrate, Guangzhou Institute of Energy Conversion ; Guangdong Natural Science Foundation ; Education Department of Hunan Province ; Development and application of nonferrous metal functional materials team
WOS SubjectEngineering, Chemical
WOS IDWOS:000430784500031
PublisherELSEVIER SCIENCE BV
Citation statistics
Cited Times:17[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/23594
Collection中国科学院广州能源研究所
Corresponding AuthorChen, Jun
Affiliation1.Xiangnan Univ, Dept Chem & Life Sci, Hunan Prov Key Lab Xiangnan Rare Precious Met Cpd, Chenzhou 423000, Hunan, Peoples R China
2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Gas Hydrate, Guangzhou 510640, Guangdong, Peoples R China
3.Liaocheng Univ, Sch Chem & Chem Engn, Liaocheng 252059, Peoples R China
4.Univ Melbourne, Sci Fac, Parkville, Vic 3050, Australia
Recommended Citation
GB/T 7714
Li, Jia-Yuan,Wang, Tao,Sun, Zhong-hui,et al. Treatment of high arsenic content lead copper matte by a pressure oxidative leaching combined with cyclone and vertical electro-deposition method[J]. SEPARATION AND PURIFICATION TECHNOLOGY,2018,199:282-288.
APA Li, Jia-Yuan.,Wang, Tao.,Sun, Zhong-hui.,Wu, Jian-Jian.,Shen, Dian-Ling.,...&Chen, Jun.(2018).Treatment of high arsenic content lead copper matte by a pressure oxidative leaching combined with cyclone and vertical electro-deposition method.SEPARATION AND PURIFICATION TECHNOLOGY,199,282-288.
MLA Li, Jia-Yuan,et al."Treatment of high arsenic content lead copper matte by a pressure oxidative leaching combined with cyclone and vertical electro-deposition method".SEPARATION AND PURIFICATION TECHNOLOGY 199(2018):282-288.
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