Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
Controllable production of guaiacols and phenols from lignin depolymerization using Pd/C catalyst cooperated with metal chloride | |
Shu, Riyang1,2; Xu, Ying2![]() ![]() ![]() | |
2018-04-15 | |
Source Publication | CHEMICAL ENGINEERING JOURNAL
![]() |
ISSN | 1385-8947 |
Volume | 338Pages:457-464 |
Corresponding Author | Zhang, Qi(zhangqi@ms.giec.ac.cn) ; Chen, Ying(chenying@gdut.edu.cn) |
Abstract | Many effective methods have been proposed to achieve lignin depolymerization, while controllable product distribution is still hard to realize. Herein, an efficient lignin hydrogenolysis process with controllable product distribution was put forward using Pd/C catalyst cooperated with metal chloride. Results showed that lignin produced a high amount of guaiacols in the presence of ZnCl2, while a high amount of phenols in the presence of CrCl3. Guaiacylglycerol-beta-guaiacyl ether was used as the model compound to carry out the mechanistic investigation. A synergetic catalysis effect between Pd/C and metal chloride was exhibited in this process. And the Lewis acidity was an important factor to determine the product distribution. With the synergetic catalysis of Pd/C and metal chloride, the dissociation energy of beta-O-4 bond was reduced significantly, which made the cleavage easier to realize. The phenolic monomer product of guaiacols was produced in the initial stage. Then CrCl3 catalyst with strong Lewis acidity could further promote the occurrence of demethoxylation and alkylation, converting the guaiacols into phenols. This work figures out the mechanism of product control in the hydrogenolysis process and displays a clear potential for the controllable valorization of lignin. |
Keyword | Lignin Hydrogenolysis Controllable product distribution beta-O-4 Synergetic catalysis Lewis acid |
DOI | 10.1016/j.cej.2018.01.002 |
WOS Keyword | AQUEOUS-PHASE HYDRODEOXYGENATION ; HYDROGENOLYSIS PROCESS ; MODEL COMPOUNDS ; HYDROLYZED LIGNIN ; AROMATIC MONOMERS ; IONIC LIQUIDS ; FORMIC-ACID ; WOOD LIGNIN ; NOBLE-METAL ; DEGRADATION |
Indexed By | SCI |
Language | 英语 |
Funding Project | Natural Science Foundation of China[51476178] ; Natural Science Foundation of China[51676191] |
WOS Research Area | Engineering |
Funding Organization | Natural Science Foundation of China |
WOS Subject | Engineering, Environmental ; Engineering, Chemical |
WOS ID | WOS:000427618400047 |
Publisher | ELSEVIER SCIENCE SA |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.giec.ac.cn/handle/344007/23273 |
Collection | 中国科学院广州能源研究所 |
Corresponding Author | Zhang, Qi; Chen, Ying |
Affiliation | 1.Guangdong Univ Technol, Sch Mat & Energy, Guangdong Prov Key Lab Funct Soft Condensed Matte, Guangzhou 510006, Guangdong, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China |
First Author Affilication | GuangZhou Institute of Energy Conversion,Chinese Academy of Sciences |
Recommended Citation GB/T 7714 | Shu, Riyang,Xu, Ying,Ma, Longlong,et al. Controllable production of guaiacols and phenols from lignin depolymerization using Pd/C catalyst cooperated with metal chloride[J]. CHEMICAL ENGINEERING JOURNAL,2018,338:457-464. |
APA | Shu, Riyang,Xu, Ying,Ma, Longlong,Zhang, Qi,Wang, Chao,&Chen, Ying.(2018).Controllable production of guaiacols and phenols from lignin depolymerization using Pd/C catalyst cooperated with metal chloride.CHEMICAL ENGINEERING JOURNAL,338,457-464. |
MLA | Shu, Riyang,et al."Controllable production of guaiacols and phenols from lignin depolymerization using Pd/C catalyst cooperated with metal chloride".CHEMICAL ENGINEERING JOURNAL 338(2018):457-464. |
Files in This Item: | There are no files associated with this item. |
Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Edit Comment