Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| Production of renewable long-chained cycloalkanes from biomass-derived furfurals and cyclic ketones | |
Liu, Qiying1 ; Zhang, Caihong1,2; Shi, Ning1,2; Zhang, Xinghua1; Wang, Chenguang1; Ma, Longlong1
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| 2018 | |
| Source Publication | RSC ADVANCES
 |
| ISSN | 2046-2069 |
| Volume | 8Issue:25Pages:13686-13696 |
| Corresponding Author | Liu, Qiying(liuqy@ms.giec.ac.cn) ; Zhang, Xinghua(zhangxh@ms.giec.ac.cn) |
| Abstract | Developing renewable long-chain cycloalkanes from lignocellulosic biomass is of significance because it offers huge resource storage, wide applications in aviation/diesel fuels and mitigation of CO2 emissions. In this paper, cycloalkanes with carbon chain lengths of 13-18 were produced from biomass-derived furfural species (furfural and 5-hydroxymethylfurfural) and cyclic ketones (cyclopentanone and cyclohexanone) via aldol condensation, followed by hydrogenation to saturate the C?C and C?O bonds, and hydrodeoxygenation to remove oxygen atoms. The aldol condensation of the furfural species with cyclic ketones was catalyzed by NaOH and the target condensation intermediates were obtained in yields of more than 90% at room temperature (30 degrees C) with a short reaction time (40 min). By using amorphous zirconium phosphate combined with Pd/C as the catalyst, liquid cycloalkanes were produced at the optimal conditions with a yield of 76%. When the combined solid catalyst was reused, the target products reduced after the second run but the initial yield could be largely recovered by recalcination of the spent zirconium phosphate. Considering that cyclopentanone and cyclohexanone can be easily produced from furfural (originating from hemicellulose) and phenol (originating from lignin), respectively, this condensation has the potential to achieve the integrated conversion of biomass-derived cellulose, hemicellulose and lignin to jet fuel and/or diesel additives. |
| DOI | 10.1039/c8ra01723a |
| WOS Keyword | HIGH-QUALITY DIESEL ; RAW LIGNOCELLULOSIC BIOMASS ; FUEL RANGE ALKANES ; DROP-IN BIOFUELS ; ZIRCONIUM-PHOSPHATE ; JET FUEL ; PLATFORM MOLECULES ; ALDOL CONDENSATION ; ANGELICA LACTONE ; LIQUID ALKANES |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | Natural Science Foundation of China[51536009] ; Natural Science Foundation of China[51576199] ; Natural Science Foundation of China[51376185] ; Natural Science Foundation of Guangdong Province[2017A030308010] |
| WOS Research Area | Chemistry |
| Funding Organization | Natural Science Foundation of China ; Natural Science Foundation of Guangdong Province |
| WOS Subject | Chemistry, Multidisciplinary |
| WOS ID | WOS:000430538300009 |
| Publisher | ROYAL SOC CHEMISTRY |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/23260 |
| Collection | 中国科学院广州能源研究所 |
| Corresponding Author | Liu, Qiying; Zhang, Xinghua |
| Affiliation | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510650, Guangdong, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| First Author Affilication | GuangZhou Institute of Energy Conversion,Chinese Academy of Sciences |
| Recommended Citation GB/T 7714 | Liu, Qiying,Zhang, Caihong,Shi, Ning,et al. Production of renewable long-chained cycloalkanes from biomass-derived furfurals and cyclic ketones[J]. RSC ADVANCES,2018,8(25):13686-13696. |
| APA | Liu, Qiying,Zhang, Caihong,Shi, Ning,Zhang, Xinghua,Wang, Chenguang,&Ma, Longlong.(2018).Production of renewable long-chained cycloalkanes from biomass-derived furfurals and cyclic ketones.RSC ADVANCES,8(25),13686-13696. |
| MLA | Liu, Qiying,et al."Production of renewable long-chained cycloalkanes from biomass-derived furfurals and cyclic ketones".RSC ADVANCES 8.25(2018):13686-13696. |
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