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Phase Equilibrium Data for the Hydrates of Synthesized Ternary CH4/CO2/N-2 Biogas Mixtures
Zang, Xiaoya1,2,3; Liang, Deqing1,2,3
2018
Source PublicationJOURNAL OF CHEMICAL AND ENGINEERING DATA
ISSN0021-9568
Volume63Issue:1Pages:197-201
Corresponding AuthorLiang, Deqing(liangdq@ms.giec.ac.cn)
AbstractTo enhance the energy efficiency of biogas and reduce environmental pollution, impurities such as CO2 and N-2 must be removed. In this context, hydrate-based gas separation (HBGS) is a novel technology that has been utilized in gas purification. As such, the hydrate phase equilibrium data of the CH4/CO2/N-2 gas mixture are crucial for application of the HBGS process in biogas separation. This study presents our investigation into the phase equilibrium conditions for the hydrates of synthesized ternary CH4/CO2/N-2 biogas mixtures. All experiments were conducted at 276.2-286.3 K and 2.59-8.84 MPa using an isochoric method with different ternary CH4/CO2/N-2 gas concentrations. The results obtained herein indicated that the hydrate phase equilibrium conditions shifted to lower pressures and higher temperatures with increasing CO2 contents. In addition, with a N-2 content of about 10%, the hydrate phase equilibrium data of the ternary gas mixtures approached that of pure CH4.
DOI10.1021/acs.jced.7b00823
WOS KeywordBROMIDE AQUEOUS-SOLUTION ; SEMICLATHRATE HYDRATE ; NATURAL-GAS ; FLUE-GAS ; METHANE SEPARATION ; CO2 CAPTURE ; CH4 ; STABILITY ; CRYSTALLIZATION ; TRANSPORTATION
Indexed BySCI
Language英语
Funding ProjectNational Natural Science Foundation of China[NSFC: 51676197] ; National Key Research and Development Plan of China[2017YFC0307305] ; CAS Program[KGZD-EW-301]
WOS Research AreaThermodynamics ; Chemistry ; Engineering
Funding OrganizationNational Natural Science Foundation of China ; National Key Research and Development Plan of China ; CAS Program
WOS SubjectThermodynamics ; Chemistry, Multidisciplinary ; Engineering, Chemical
WOS IDWOS:000422813400022
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:16[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/22832
Collection中国科学院广州能源研究所
Corresponding AuthorLiang, Deqing
Affiliation1.Chinese Acad Sci, Guangzhou Ctr Gas Hydrate Res, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China
2.CAS Key Lab Gas Hydrate, Guangzhou 510640, Guangdong, Peoples R China
3.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Guangdong, Peoples R China
Recommended Citation
GB/T 7714
Zang, Xiaoya,Liang, Deqing. Phase Equilibrium Data for the Hydrates of Synthesized Ternary CH4/CO2/N-2 Biogas Mixtures[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA,2018,63(1):197-201.
APA Zang, Xiaoya,&Liang, Deqing.(2018).Phase Equilibrium Data for the Hydrates of Synthesized Ternary CH4/CO2/N-2 Biogas Mixtures.JOURNAL OF CHEMICAL AND ENGINEERING DATA,63(1),197-201.
MLA Zang, Xiaoya,et al."Phase Equilibrium Data for the Hydrates of Synthesized Ternary CH4/CO2/N-2 Biogas Mixtures".JOURNAL OF CHEMICAL AND ENGINEERING DATA 63.1(2018):197-201.
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