Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| Ni/La2O2CO3催化剂对山梨醇氢解产物的选择性调控 | |
| Alternative Title | Selective hydrogenolysis of sorbitol on Ni/La202CO3 catalysts |
张涛1,2; 刘琪英1 ; 张彩红2,3; 张琦1; 马隆龙1
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| 2017-06 | |
| Source Publication | 化工学报
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| ISSN | 0438-1157 |
| Volume | 68Issue:6Pages:2359-2367 |
| Abstract | 采用共沉淀法制各了具有协同稳定作用的Ni/La2O2CO3催化剂，用于山梨醇选择性氢解为小分子醇的研究。采用X射线衍射、氢气程序升温还原、C02程序升温脱附和扫描电镜对催化剂进行了表征。考察了不同配比Ni、La的加氢位点和碱性调控对山梨醇氢解产物的影响。结果表明，Ni、La摩尔比为2：3时，山梨醇转化率达到98.6%，C2~c3多元醇的产率达到43.8%，催化剂经2次反应后对山梨醇的转化率仍高达90%。探究了催化剂从酸性到碱性调变过程中，山梨醇氢解的产物分布，并提出了反应路径。 |
| Other Abstract | Ni/La2O2CO3 catalysts with different Ni/La ratios were prepared by co-precipitation and the performance was tested in selective hydrogenolysis of sorbitol to C2--C3 polyols. The catalysts were characterized by X-ray diffraction(XRD), H2 temperature-programmed reduction(H2-TPR), CO2 temperature-programmed desorption(CO2-TPD) and scanning electron microscopy (SEM). The effect of hydrogenation and base regulation was investigated by varying the Ni / La ratios. The result shows that the conversion of sorbitol was 98.6% and the yields of C2-C3 polyols was 43.8% when the mole ratio of Ni to La is 2:3. After two times of reaction, the catalyst still achieved a sorbitol conversion of 90%. From acidic to alkaline, the products distribution of hydrogenolysis of sorbitol was discussed. The reaction pathway was also proposed based on the experiment results. |
| Keyword | 山梨醇 选择性催化还原 纳米材料 加氢 共沉淀 C2~C3多元醇 sorbitol SCR nanomaterials hydrothermal co-precipitation C2--C3 polyols |
| DOI | 10.11949/j.issn.0438-1157.20170043 |
| Language | 中文 |
| CSCD ID | CSCD:5994221 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/16526 |
| Collection | 中国科学院广州能源研究所 |
| Corresponding Author | 刘琪英 |
| Affiliation | 1.中国科学院广州能源研究所，可再生能源与天然气水合物重点实验室，广东广州510640; 2.中国科学技术大学纳米科学技术学院，江苏苏州215123; 3.中国科学院大学，北京100049 |
| First Author Affilication | 天然气水合物 |
| Recommended Citation GB/T 7714 | 张涛,刘琪英,张彩红,等. Ni/La2O2CO3催化剂对山梨醇氢解产物的选择性调控[J]. 化工学报,2017,68(6):2359-2367. |
| APA | 张涛,刘琪英,张彩红,张琦,&马隆龙.(2017).Ni/La2O2CO3催化剂对山梨醇氢解产物的选择性调控.化工学报,68(6),2359-2367. |
| MLA | 张涛,et al."Ni/La2O2CO3催化剂对山梨醇氢解产物的选择性调控".化工学报 68.6(2017):2359-2367. |
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| Ni_La2O2CO3催化剂对山梨醇氢解（5043KB） | 期刊论文 | 出版稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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