Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| Production of furfural from xylose and corn stover catalyzed by a novel porous carbon solid acid in gamma-valerolactone | |
Zhu, Yuanshuai1; Li, Wenzhi1; Lu, Yijuan1; Zhang, Tingwei1; Jameel, Hasan2; Chang, Hou-min2; Ma, Longlong3
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| 2017 | |
| Source Publication | RSC ADVANCES
 |
| Volume | 7Issue:48Pages:29916-29924 |
| Abstract | A resorcinol-formaldehyde resin carbon (RFC) catalyst with a well-developed, ordered, mesoporous framework was prepared using a soft template method at room temperature. The carbon was sulfonated in water using sulfanilic acid under mild atmospheric conditions. The sulfonated RFC (S-RFC) was characterized by N-2 adsorption-desorption, elemental analysis, TEM, XPS, and FT-IR. It was determined that S-RFC is an efficient solid acid catalyst for furfural production from xylose and corn stover in gamma-valerolactone (GVL). The effects of reaction time, reaction temperature, catalyst loading, substrate dosage and water concentration were investigated. 80% furfural yield and 100% xylose conversion were obtained from xylose at 170 degrees C in 15 min with 0.5 g catalyst. Comparatively, 68.6% furfural yield was achieved from corn stover at 200 degrees C in 100 min when using 0.6 g catalyst. Since there was no discernable decrease in furfural yield after multiple conversions utilizing the same catalyst, the recyclability of the catalyst is considered good. |
| Subtype | Article |
| WOS Headings | Science & Technology ; Physical Sciences |
| DOI | 10.1039/c7ra03995f |
| WOS Subject Extended | Chemistry |
| WOS Keyword | MICROWAVE-ASSISTED DEHYDRATION ; ORDERED MESOPOROUS CARBON ; LIGNOCELLULOSIC BIOMASS ; AQUEOUS-PHASE ; BIPHASIC SYSTEM ; LEVULINIC ACID ; CONVERSION ; LIQUID ; CHEMICALS ; HYDROGENATION |
| Indexed By | SCI |
| Language | 英语 |
| Funding Organization | State Key Program of National Natural Science Foundation of China(51536009) ; National Key Technology R&D Program of China(2015BAD15B06) ; international technology cooperation plan of Anhui(1503062030) |
| WOS Subject | Chemistry, Multidisciplinary |
| WOS ID | WOS:000403565400001 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/14155 |
| Collection | 中国科学院广州能源研究所 |
| Affiliation | 1.Univ Sci & Technol China, Dept Thermal Sci & Energy Engn, Lab Basic Res Biomass Convers & Utilizat, Hefei 230026, Peoples R China 2.North Carolina State Univ, Dept Forest Biomat, Raleigh, NC 27695 USA 3.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China |
| Recommended Citation GB/T 7714 | Zhu, Yuanshuai,Li, Wenzhi,Lu, Yijuan,et al. Production of furfural from xylose and corn stover catalyzed by a novel porous carbon solid acid in gamma-valerolactone[J]. RSC ADVANCES,2017,7(48):29916-29924. |
| APA | Zhu, Yuanshuai.,Li, Wenzhi.,Lu, Yijuan.,Zhang, Tingwei.,Jameel, Hasan.,...&Ma, Longlong.(2017).Production of furfural from xylose and corn stover catalyzed by a novel porous carbon solid acid in gamma-valerolactone.RSC ADVANCES,7(48),29916-29924. |
| MLA | Zhu, Yuanshuai,et al."Production of furfural from xylose and corn stover catalyzed by a novel porous carbon solid acid in gamma-valerolactone".RSC ADVANCES 7.48(2017):29916-29924. |
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