Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| The effect of tetrabutylphosphonium bromide on the formation process of CO2 hydrates | |
Shi, Lingli1,2,3; Yi, Lizhi1,2,3; Shen, Xiaodong1,2,3,4; Wu, Wenzhi1,2,3,4; Liang, Deqing1,2,3
| |
| 2017-03-01 | |
| Source Publication | JOURNAL OF MOLECULAR LIQUIDS
 |
| Volume | 229Pages:98-105 |
| Abstract | Quaternary salts can form semiclathrate hydrates with vacant cages to capture gas molecules, such as CO2. To study the effect in the formation process of CO2 hydrates, the formation kinetics of tetrabutylphosphonium bromide (TBPB) + CO2 hydrate were investigated in this work. The study was conducted by employing an isobaric method with salt mass fraction and subcooling degree ranging from (0.10 to 0.60) and from (8 K to 10 K), respectively. The kinetic performance of TBPB was evaluated by the induction time, normalized gas consumption, and normalized gas consumption rate. The results showed that the induction time decreased with the increase of subcooling degree as well as the salt mass fraction. When salt mass fraction exceeded 0.20, the average induction times were particularly short and almost the same. In addition, the salt mass fraction had a great impact on the normalized gas consumption rather than the normalized gas consumption rate. (C)2016 Elsevier B.V. All rights reserved. |
| Subtype | Article |
| Keyword | Tetrabutylphosphonium Bromide Co2 Capture And Storage Hydrate Formation Kinetics |
| WOS Headings | Science & Technology ; Physical Sciences |
| DOI | 10.1016/j.molliq.2016.12.038 |
| WOS Subject Extended | Chemistry ; Physics |
| WOS Keyword | PLUS CARBON-DIOXIDE ; N-BUTYLAMMONIUM BROMIDE ; PHASE-EQUILIBRIUM DATA ; GUEST GAS ENCLATHRATION ; BUTYL AMMONIUM-CHLORIDE ; AQUEOUS-SOLUTION SYSTEMS ; SIMULATED FLUE-GAS ; SEMICLATHRATE HYDRATE ; CLATHRATE HYDRATE ; DISSOCIATION CONDITIONS |
| Indexed By | SCI |
| Language | 英语 |
| Funding Organization | National Natural Science Foundation of China(51376182) ; Guangdong Natural Sciences of Foundation(2016A030310126) ; Key Laboratory of Gas Hydrate ; Guangzhou Institute of Energy Conversion ; Chinese Academy of Sciences(Y607jb1001) |
| WOS Subject | Chemistry, Physical ; Physics, Atomic, Molecular & Chemical |
| WOS ID | WOS:000395598800012 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/14099 |
| Collection | 中国科学院广州能源研究所 |
| Affiliation | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 2.Chinese Acad Sci, CAS Key Lab Gas Hydrate, Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Guangdong, Peoples R China 3.Chinese Acad Sci, Guangzhou Ctr Gas Hydrate Res, Guangzhou 510640, Guangdong, Peoples R China 4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| First Author Affilication | GuangZhou Institute of Energy Conversion,Chinese Academy of Sciences |
| Recommended Citation GB/T 7714 | Shi, Lingli,Yi, Lizhi,Shen, Xiaodong,et al. The effect of tetrabutylphosphonium bromide on the formation process of CO2 hydrates[J]. JOURNAL OF MOLECULAR LIQUIDS,2017,229:98-105. |
| APA | Shi, Lingli,Yi, Lizhi,Shen, Xiaodong,Wu, Wenzhi,&Liang, Deqing.(2017).The effect of tetrabutylphosphonium bromide on the formation process of CO2 hydrates.JOURNAL OF MOLECULAR LIQUIDS,229,98-105. |
| MLA | Shi, Lingli,et al."The effect of tetrabutylphosphonium bromide on the formation process of CO2 hydrates".JOURNAL OF MOLECULAR LIQUIDS 229(2017):98-105. |
| Files in This Item: | There are no files associated with this item. | |||||
Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Edit Comment