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Fast Pyrolysis of Nitrogen-Rich Wood Waste Pretreated by Microwave-Assisted Glycerolysis
Zheng, Anqing1,2,3; Zhao, Kun1,2,3; Zhao, Zengli1,2,3; Jiang, Liqun1,2,3; Huang, Zhen1,2,3; Wei, Guoqiang1,2,3; Wang, Xiaobo1,2,3; He, Fang1,2,3; Li, Haibin1,2,3
2017-03-01
Source PublicationWASTE AND BIOMASS VALORIZATION
Volume8Issue:2Pages:349-358
AbstractThe high nitrogen content in wood waste containing urea formaldehyde from furniture industry hampers its utilization as a clean fuel. Herein, microwave-assisted organosolv pretreatment of wood waste using glycerol as solvent was conducted in a commercial microwave reactor with varying temperature of 120-240 degrees C for reducing nitrogen content. The elemental analysis shows that up to 88.1 % of nitrogen and 92.9 % of alkali and alkaline earth metals in wood waste can be removed by microwave-assisted glycerolysis. The solid nuclear magnetic resonance spectrometry analysis illustrate that the urea-formaldehyde resin, lignin and hemicellulose fractions in wood waste can also be simultaneously reduced by pretreatment. Raw and pretreated wood waste was subsequently fast pyrolyzed in a semi-batch pyroprobe reactor. The experimental results demonstrate that the relative content of levoglucosan in pyrolysis vapors was significantly enhanced by pretreatment, whereas the relative content of nitrogen-containing compounds was reduced obviously. These findings provide a simple and efficient pretreatment method for reducing the formation of nitrogenous compounds during fast pyrolysis of nitrogen-rich wood waste.
SubtypeArticle
KeywordWood Waste Microwave Pretreatment Organosolv Pretreatment Nitrogen Removal Fast Pyrolysis Sugar Production
WOS HeadingsScience & Technology ; Life Sciences & Biomedicine
DOI10.1007/s12649-016-9578-1
WOS Subject ExtendedEnvironmental Sciences & Ecology
WOS KeywordMELAMINE-FORMALDEHYDE RESINS ; UREA-FORMALDEHYDE ; BIO-OIL ; BIOMASS ; TORREFACTION ; TEMPERATURE ; EMISSION ; LIGNIN
Indexed BySCI
Language英语
Funding OrganizationNational Natural Science Foundation of China(51376186 ; Natural Science Foundation of Guangdong Province, China(2014A030313672) ; Science and Technology Planning Project of Guangdong Province, China(2014B020216004 ; 21406227) ; 2015A020215024)
WOS SubjectEnvironmental Sciences
WOS IDWOS:000394351600009
Citation statistics
Cited Times:3[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/14092
Collection中国科学院广州能源研究所
Affiliation1.Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China
3.Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou 510640, Guangdong, Peoples R China
First Author AffilicationGuangZhou Institute of Energy Conversion,Chinese Academy of Sciences
Recommended Citation
GB/T 7714
Zheng, Anqing,Zhao, Kun,Zhao, Zengli,et al. Fast Pyrolysis of Nitrogen-Rich Wood Waste Pretreated by Microwave-Assisted Glycerolysis[J]. WASTE AND BIOMASS VALORIZATION,2017,8(2):349-358.
APA Zheng, Anqing.,Zhao, Kun.,Zhao, Zengli.,Jiang, Liqun.,Huang, Zhen.,...&Li, Haibin.(2017).Fast Pyrolysis of Nitrogen-Rich Wood Waste Pretreated by Microwave-Assisted Glycerolysis.WASTE AND BIOMASS VALORIZATION,8(2),349-358.
MLA Zheng, Anqing,et al."Fast Pyrolysis of Nitrogen-Rich Wood Waste Pretreated by Microwave-Assisted Glycerolysis".WASTE AND BIOMASS VALORIZATION 8.2(2017):349-358.
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