Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| Aqueous-Phase Hydrodeoxygenation of Biomass Sugar Alcohol into Renewable Alkanes over a Carbon-Supported Ruthenium with Phosphoric Acid Catalytic System | |
Weng, Yujing1,2; Wang, Tiejun1 ; Qiu, Songbai1; Wang, Chenguang1; Ma, Longlong1; Zhang, Qi1; Chen, Lungang1; Li, Yuping1; Sun, Fei1; Zhang, Qian1,2
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| 2017-03-01 | |
| Source Publication | CHEMCATCHEM
 |
| Volume | 9Issue:5Pages:774-781 |
| Abstract | Recently, we demonstrated the catalytic conversion of biomass hydrolysate and real biomass into renewable alkanes over a Ru/C catalyst with aqueous phosphoric acid (Ru/C+H3PO4) and we obtained a high yield of C-5/C-6 alkanes. In this study, the mechanism of sorbitol hydrodeoxygenation (HDO) into alkanes over the Ru/C+H3PO4 catalytic system was investigated by using a trickle-bed reactor. A high HDO performance was detected with a large amount of long-chain alkanes in the products. Subsequently, pre- and postcharacterization studies (N-2 adsorption, XRD, X-ray photoelectron spectroscopy, TEM, NH3 temperature-programmed desorption, H-2 temperature-programmed reduction, FTIR spectroscopy) were performed on the relevant catalysts to study the change of the catalytic active sites. Moreover, mineral acid experiments were performed to study the influence of phosphoric acid on the HDO performance. |
| Subtype | Article |
| Keyword | Alcohols Alkanes Biomass Ruthenium Supported Catalysts |
| WOS Headings | Science & Technology ; Physical Sciences |
| DOI | 10.1002/cctc.201601470 |
| WOS Subject Extended | Chemistry |
| WOS Keyword | STABLE HETEROGENEOUS CATALYSTS ; TRANSFER HYDROGENATION ; RU/C CATALYST ; SORBITOL TRANSFORMATION ; LIGNOCELLULOSIC BIOMASS ; OXYGEN REDUCTION ; CONVERSION ; PHOSPHATE ; DEHYDRATION ; EFFICIENT |
| Indexed By | SCI |
| Language | 英语 |
| Funding Organization | National Natural Science Foundation of China(51476176 ; key program of Chinese Academy of Sciences(KGZD-EW-304-2) ; Guangdong province special Talent support plan(511054728068) ; 51536009) |
| WOS Subject | Chemistry, Physical |
| WOS ID | WOS:000395799000009 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/14085 |
| Collection | 中国科学院广州能源研究所 |
| Affiliation | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangdong Prov Key Lab New & Renewable Energy Res, Key Lab Renewable Energy, Nengyuan Rd 2, Guangzhou 510640, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| First Author Affilication | GuangZhou Institute of Energy Conversion,Chinese Academy of Sciences |
| Recommended Citation GB/T 7714 | Weng, Yujing,Wang, Tiejun,Qiu, Songbai,et al. Aqueous-Phase Hydrodeoxygenation of Biomass Sugar Alcohol into Renewable Alkanes over a Carbon-Supported Ruthenium with Phosphoric Acid Catalytic System[J]. CHEMCATCHEM,2017,9(5):774-781. |
| APA | Weng, Yujing.,Wang, Tiejun.,Qiu, Songbai.,Wang, Chenguang.,Ma, Longlong.,...&Zhang, Qian.(2017).Aqueous-Phase Hydrodeoxygenation of Biomass Sugar Alcohol into Renewable Alkanes over a Carbon-Supported Ruthenium with Phosphoric Acid Catalytic System.CHEMCATCHEM,9(5),774-781. |
| MLA | Weng, Yujing,et al."Aqueous-Phase Hydrodeoxygenation of Biomass Sugar Alcohol into Renewable Alkanes over a Carbon-Supported Ruthenium with Phosphoric Acid Catalytic System".CHEMCATCHEM 9.5(2017):774-781. |
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