Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| Synergistic effects of highly active Ni and acid site on the hydrodeoxygenation of syringol | |
Shu, Riyang1,2,3,4; Xu, Ying1,2,3 ; Ma, Longlong1,2,3; Zhang, Qi1,2,3; Chen, Pengru1,2,3,4; Wang, Tiejun1,2,3
| |
| 2017-03-05 | |
| Source Publication | CATALYSIS COMMUNICATIONS
 |
| Volume | 91Pages:1-5 |
| Abstract | The hydrodeoxygenation of syringol was explored with novel step by step precipitated Ni/SiO2-Al2O3 catalyst under mild conditions. Demethoxylation and dehydroxylation occurred in the first step, followed by the hydrogenation of benzene. Cyclohexane was formed eventually. Ni/SiO2-Al2O3 catalyst possessed high nickel dispersion and high amounts of acid sites. The synergistic effects of highly active Ni and acid site were the key to realize the occurrence of deoxygenation. These specialties resulted in the complete conversion of syringol at 200 degrees C, with the cyclohexane selectivity up to 97.8%, much better than the hydrodeoxygenation performances of single Ni/SiO2 and Ni/Al2O3. (C) 2016 Published by Elsevier B.V. |
| Subtype | Article |
| Keyword | Ni/sio2-al2o3 Hydrodeoxygenation Syringol Acid Site Synergistic Effects |
| WOS Headings | Science & Technology ; Physical Sciences |
| DOI | 10.1016/j.catcom.2016.12.006 |
| WOS Subject Extended | Chemistry |
| WOS Keyword | GUAIACOL HYDRODEOXYGENATION ; PHENOLIC-COMPOUNDS ; LIGNIN ; CATALYSTS ; HYDROGENOLYSIS ; HYDROGENATION ; DEPOLYMERIZATION ; TEMPERATURE ; EFFICIENT |
| Indexed By | SCI |
| Language | 英语 |
| Funding Organization | Natural Science Foundation of China(51476178 ; Youth Science and Technology Innovation Talents Plan of Guangdong Provinc(2015TQ01N652) ; Youth Innovation Promotion Association Chinese Academy of Sciences ; 51676191) |
| WOS Subject | Chemistry, Physical |
| WOS ID | WOS:000394064000001 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/14071 |
| Collection | 中国科学院广州能源研究所 |
| Affiliation | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 2.Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 3.Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou 510640, Guangdong, Peoples R China 4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| First Author Affilication | GuangZhou Institute of Energy Conversion,Chinese Academy of Sciences |
| Recommended Citation GB/T 7714 | Shu, Riyang,Xu, Ying,Ma, Longlong,et al. Synergistic effects of highly active Ni and acid site on the hydrodeoxygenation of syringol[J]. CATALYSIS COMMUNICATIONS,2017,91:1-5. |
| APA | Shu, Riyang,Xu, Ying,Ma, Longlong,Zhang, Qi,Chen, Pengru,&Wang, Tiejun.(2017).Synergistic effects of highly active Ni and acid site on the hydrodeoxygenation of syringol.CATALYSIS COMMUNICATIONS,91,1-5. |
| MLA | Shu, Riyang,et al."Synergistic effects of highly active Ni and acid site on the hydrodeoxygenation of syringol".CATALYSIS COMMUNICATIONS 91(2017):1-5. |
| Files in This Item: | There are no files associated with this item. | |||||
Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Edit Comment