Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| High conversion of glucose to 5-hydroxymethylfurfural using hydrochloric acid as a catalyst and sodium chloride as a promoter in a water/gamma-valerolactone system | |
Li, Minghao1; Li, Wenzhi1; Lu, Yijuan1; Jameel, Hasan2; Chang, Hou-min2; Ma, Longlong3
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| 2017 | |
| Source Publication | RSC ADVANCES
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| Volume | 7Issue:24Pages:14330-14336 |
| Abstract | Biomass derived 5-hydroxymethylfurfural (HMF) is regarded as an important platform molecule for the synthesis of value-added chemicals and fuels, but the high production cost has always been a bottleneck for the industrial scale use of HMF. Different mineral acids (HCl and H2SO4) being used as the catalyst and different salts being used as the reaction promoter were evaluated. It was found that HCl, in combination with NaCl, in a water/gamma-valerolactone system showed high selectivity and impressive efficiency for the synthesis of HMF from glucose. The optimal conditions to obtain the best HMF yield (62.45%) were 0.2 M HCl and 0.1 M NaCl at 140 degrees C with a residence time of 60 minutes. An 18.22% molar yield of LA was obtained as a by-product. The effect of different anions was also investigated, and it was determined that not only the hydrogen ions, but also the nature of the acid and the type of salt played a joint role in improving the HMF yield. In addition, a possible synthesis pathway was proposed for large scale production of HMF. |
| Subtype | Article |
| WOS Headings | Science & Technology ; Physical Sciences |
| DOI | 10.1039/c7ra00701a |
| WOS Subject Extended | Chemistry |
| WOS Keyword | LEVULINIC ACID ; GAMMA-VALEROLACTONE ; BIPHASIC SYSTEM ; LIGNOCELLULOSIC BIOMASS ; SELECTIVE CONVERSION ; DEHYDRATION ; CELLULOSE ; CHEMICALS ; FRUCTOSE ; WATER |
| Indexed By | SCI |
| Language | 英语 |
| Funding Organization | National Key Technology R&D Program of China(2015BAD15B06) ; Science and Technological Fund of Anhui Province for Outstanding Youth(1508085J01) ; international technology cooperation plan of Anhui(1503062030) |
| WOS Subject | Chemistry, Multidisciplinary |
| WOS ID | WOS:000396150900005 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/14064 |
| Collection | 中国科学院广州能源研究所 |
| Affiliation | 1.Univ Sci & Technol China, Dept Thermal Sci & Energy Engn, Hefei 230026, Peoples R China 2.North Carolina State Univ, Dept Forest Biomat, Raleigh, NC 27695 USA 3.Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China |
| Recommended Citation GB/T 7714 | Li, Minghao,Li, Wenzhi,Lu, Yijuan,et al. High conversion of glucose to 5-hydroxymethylfurfural using hydrochloric acid as a catalyst and sodium chloride as a promoter in a water/gamma-valerolactone system[J]. RSC ADVANCES,2017,7(24):14330-14336. |
| APA | Li, Minghao,Li, Wenzhi,Lu, Yijuan,Jameel, Hasan,Chang, Hou-min,&Ma, Longlong.(2017).High conversion of glucose to 5-hydroxymethylfurfural using hydrochloric acid as a catalyst and sodium chloride as a promoter in a water/gamma-valerolactone system.RSC ADVANCES,7(24),14330-14336. |
| MLA | Li, Minghao,et al."High conversion of glucose to 5-hydroxymethylfurfural using hydrochloric acid as a catalyst and sodium chloride as a promoter in a water/gamma-valerolactone system".RSC ADVANCES 7.24(2017):14330-14336. |
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