Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| Depolymerization of Organosolv Lignin over Silica-alumina Catalysts | |
Wu, Qing-yun1,2; Ma, Long-long1,2 ; Long, Jin-xing2; Shu, Ri-yang2,3; Zhang, Qi2; Wang, Tie-jun2; Xu, Ying2
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| 2016-08-01 | |
| Source Publication | CHINESE JOURNAL OF CHEMICAL PHYSICS
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| Volume | 29Issue:4Pages:474-480 |
| Abstract | Efficient conversion of lignin to fine chemicals and biofuel become more and more attractive in biorefinery. In this work, we used a series of silica-alumina catalysts (i.e., SiO2-Al2O3, HY, H beta, and HZSM-5) to degrade lignin into arenes and phenols. The relationship between the catalyst structure and lignin depolymerization performance was investigated. The results showed that both acidity and pore size of the catalyst could influence the conversion of lignin. In the volatilizable product, phenols were identified as the main phenolic monomers via gas chromatography-mass spectrometer. SiO2-Al2O3 was the most efficient catalyst, giving 90.96% degree of conversion, 12.91% yield of phenols, and 2.41% yield of arenes in ethanol at 280 degrees C for 4 h. The Fourier transform infrared spectroscopy and H-1 nuclear magnetic resonance spectroscopy analysis demonstrated that deoxygenation and alkylation occurred in this process. The effect of solvents was also investigated and the results showed that ethanol was the most efficient solvent. |
| Subtype | Article |
| Keyword | Lignin Sio2-al2o3 Phenols Deoxygenation Alkylation |
| WOS Headings | Science & Technology ; Physical Sciences |
| DOI | 10.1063/1674-0068/29/cjcp1601017 |
| WOS Subject Extended | Physics |
| WOS Keyword | SOLID ACID CATALYSTS ; KRAFT LIGNIN ; CHEMICALS ; VALORIZATION ; HYDROGENOLYSIS ; ETHANOLYSIS ; EFFICIENT |
| Indexed By | SCI |
| Language | 英语 |
| Funding Organization | National Key Technology RD Program(2014BAD02B01) ; National Natural Science Foundation of China(51476178) |
| WOS Subject | Physics, Atomic, Molecular & Chemical |
| WOS ID | WOS:000383114400011 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/11840 |
| Collection | 中国科学院广州能源研究所 |
| Affiliation | 1.Univ Sci & Technol China, Dept Chem, Hefei 230026, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| First Author Affilication | GuangZhou Institute of Energy Conversion,Chinese Academy of Sciences |
| Recommended Citation GB/T 7714 | Wu, Qing-yun,Ma, Long-long,Long, Jin-xing,et al. Depolymerization of Organosolv Lignin over Silica-alumina Catalysts[J]. CHINESE JOURNAL OF CHEMICAL PHYSICS,2016,29(4):474-480. |
| APA | Wu, Qing-yun.,Ma, Long-long.,Long, Jin-xing.,Shu, Ri-yang.,Zhang, Qi.,...&Xu, Ying.(2016).Depolymerization of Organosolv Lignin over Silica-alumina Catalysts.CHINESE JOURNAL OF CHEMICAL PHYSICS,29(4),474-480. |
| MLA | Wu, Qing-yun,et al."Depolymerization of Organosolv Lignin over Silica-alumina Catalysts".CHINESE JOURNAL OF CHEMICAL PHYSICS 29.4(2016):474-480. |
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