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| Dissociation Temperatures of Mixed Semiclathrate Hydrates Formed with Tetrabutylammonium Bromide Plus Tetrabutylammonium Chloride | |
Shi, Lingli1,2; Yi, Lizhi1,2; Shen, Xiaodong1,2,3; Wu, Wenzhi1,2,3; Liang, Deqing1,2
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| 2016-06-01 | |
| Source Publication | JOURNAL OF CHEMICAL AND ENGINEERING DATA
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| Volume | 61Issue:6Pages:2155-2159 |
| Abstract | Dissociation temperatures of mixed tetrabutylammonium bromide (TBAB) + tetrabutylammonium chloride (TBAC) semiclathrate hydrates were determined by using the DSC technique. The system was measured in five groups with a fixed total mole fraction (x = 0.0100, 0.0200, and 0.0337), TBAB mole fraction (x(TBAB) = 0.0370) or TBAC mole fraction (x(TBAC) = 0.0337). The obtained results demonstrated that at a given x, the dissociation temperatures of mixed (TBAB + TBAC) semiclathrate hydrates were all higher than that of pure TBAB hydrate, and the maximum dissociation temperature appeared at x(TBAB)/x = 0.25 instead of x(TBAB)/x = 0 or 1 (corresponding to pure TBAC or TBAB hydrate). In addition, for systems with fixed x(TBAB) or x(TBAC), TBAC gained the control of forming TBAC semiclathrate hydrate preferentially. |
| Subtype | Article |
| WOS Headings | Science & Technology ; Physical Sciences ; Technology |
| DOI | 10.1021/acs.jced.6b00106 |
| WOS Subject Extended | Thermodynamics ; Chemistry ; Engineering |
| WOS Keyword | N-BUTYLAMMONIUM BROMIDE ; BUTYL AMMONIUM BROMIDE ; PHASE-EQUILIBRIA ; CLATHRATE HYDRATE ; CARBON-DIOXIDE ; TETRABUTYLPHOSPHONIUM BROMIDE ; THERMODYNAMIC PROPERTIES ; COLD-STORAGE ; LATENT-HEAT ; CO2 |
| Indexed By | SCI |
| Language | 英语 |
| WOS Subject | Thermodynamics ; Chemistry, Multidisciplinary ; Engineering, Chemical |
| WOS ID | WOS:000377841600023 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/11753 |
| Collection | 中国科学院广州能源研究所 |
| Affiliation | 1.Chinese Acad Sci, Key Lab Nat Gas Hydrate, Guangzhou 510640, Guangdong, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou 510640, Guangdong, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| First Author Affilication | GuangZhou Institute of Energy Conversion,Chinese Academy of Sciences |
| Recommended Citation GB/T 7714 | Shi, Lingli,Yi, Lizhi,Shen, Xiaodong,et al. Dissociation Temperatures of Mixed Semiclathrate Hydrates Formed with Tetrabutylammonium Bromide Plus Tetrabutylammonium Chloride[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA,2016,61(6):2155-2159. |
| APA | Shi, Lingli,Yi, Lizhi,Shen, Xiaodong,Wu, Wenzhi,&Liang, Deqing.(2016).Dissociation Temperatures of Mixed Semiclathrate Hydrates Formed with Tetrabutylammonium Bromide Plus Tetrabutylammonium Chloride.JOURNAL OF CHEMICAL AND ENGINEERING DATA,61(6),2155-2159. |
| MLA | Shi, Lingli,et al."Dissociation Temperatures of Mixed Semiclathrate Hydrates Formed with Tetrabutylammonium Bromide Plus Tetrabutylammonium Chloride".JOURNAL OF CHEMICAL AND ENGINEERING DATA 61.6(2016):2155-2159. |
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