Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| Production of 5-Hydroxymethylfurfural and Furfural from Lignocellulosic Biomass in Water-Tetrahydrofuran Media with Sodium Bisulfate | |
Shi, Ning1,2; Liu, Qi-ying1; Wang, Tie-jun1 ; Zhang, Qi1; Ma, Long-long1; Cai, Chi-liu1
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| 2015-10-01 | |
| Source Publication | CHINESE JOURNAL OF CHEMICAL PHYSICS
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| Volume | 28Issue:5 |
| Abstract | 5-Hydroxymethylfurfural (HMF) and furfural (FF), two bio-based platform chemicals, were produced from various raw lignocellulosic materials (corncob, corn stover, wheat straw, rice straw and sugarcane bagasse) in a water-tetrahydrofuran media by using NaHSO4 as catalyst. The influences of reaction temperature (160-200 degrees C), reaction time (30-120 min), solvent volume ratio, feedstock concentration (2.4wt%-11.1wt%) and catalyst dosage were studied. The highest HMF and FF yields obtained from corncob were 47mol% and 56mol% under condition of 190 degrees C, 90 min, 10/1 of THF/H2O. Besides, the lignin in the raw biomass was also depolymerized into organosolv lignin. |
| Subtype | Article |
| Keyword | 5-hydroxymethylfurfural Furfural Lignocellulosic Biomass Hydrolysis Dehydration Tetrahydrofuran Sodium Bisulfate |
| WOS Headings | Science & Technology ; Physical Sciences |
| DOI | 10.1063/1674-0068/28/cjcp1501008 |
| WOS Subject Extended | Physics |
| WOS Keyword | STRUCTURAL-CHARACTERIZATION ; CATALYTIC CONVERSION ; IONIC LIQUIDS ; CHEMICALS ; CELLULOSE ; ACID ; ORGANOSOLV ; LIGNIN ; PRETREATMENT ; SUGARS |
| Indexed By | SCI |
| Language | 英语 |
| WOS Subject | Physics, Atomic, Molecular & Chemical |
| WOS ID | WOS:000364503400018 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/10891 |
| Collection | 中国科学院广州能源研究所 |
| Affiliation | 1.Chinese Acad Sci, CAS Key Lab Renewable Energy, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 2.Guizhou Inst Technol, Sch Chem Engn, Guiyang 550003, Peoples R China |
| Recommended Citation GB/T 7714 | Shi, Ning,Liu, Qi-ying,Wang, Tie-jun,et al. Production of 5-Hydroxymethylfurfural and Furfural from Lignocellulosic Biomass in Water-Tetrahydrofuran Media with Sodium Bisulfate[J]. CHINESE JOURNAL OF CHEMICAL PHYSICS,2015,28(5). |
| APA | Shi, Ning,Liu, Qi-ying,Wang, Tie-jun,Zhang, Qi,Ma, Long-long,&Cai, Chi-liu.(2015).Production of 5-Hydroxymethylfurfural and Furfural from Lignocellulosic Biomass in Water-Tetrahydrofuran Media with Sodium Bisulfate.CHINESE JOURNAL OF CHEMICAL PHYSICS,28(5). |
| MLA | Shi, Ning,et al."Production of 5-Hydroxymethylfurfural and Furfural from Lignocellulosic Biomass in Water-Tetrahydrofuran Media with Sodium Bisulfate".CHINESE JOURNAL OF CHEMICAL PHYSICS 28.5(2015). |
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