Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| Sorbitol transformation into aromatics: A comparative evaluation of Ni/HZSM-5 and Ni/H beta | |
| Zhang, Qing1,2; Tan, Jin1; Wang, Tiejun1; Zhang, Qi1; Ma, Longlong1; Qiu, Songbai1; Weng, Yujing1 | |
| 2016-02-01 | |
| Source Publication | FUEL
 |
| Volume | 165 |
| Abstract | Aromatics including benzenes, olefins and naphthalenes derived from renewable biomass are of great importance on the potential substitution for diminishing fossil fuels. In this work, aromatics from biomass-derived sorbitol by hydrogenation and aromatization was investigated over the Ni/HZSM-5 and Ni/H beta catalysts in a fixed-bed reactor. The testing results showed that all the catalysts revealed 100% of sorbitol conversion, while the formation of aromatics and carbon species were various during the catalytic processing of sorbitol. The selectivity of aromatics was found to be 53.2% and 17.1% over the Ni/HZSM-5(38) and Ni/H beta catalyst, respectively. In addition, the catalysts were characterized by N-2 physical adsorption, X-ray powder diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), H-2 temperature-programmed reduction (H-2-TPR), and temperature-programmed desorption of ammonia (NH3-TPD) techniques. The characterization results revealed that the Ni/HZSM-5(38) catalyst contained the optimum acidic sites and the structural property, which favor the hydrogenation and aromatization of sorbitol in the reaction. (C) 2015 Elsevier Ltd. All rights reserved. |
| Subtype | Article |
| Keyword | Sorbitol Aromatics Ni/hzsm-5 Ni/h Beta Catalyst Characterization |
| WOS Headings | Science & Technology ; Technology |
| DOI | 10.1016/j.fuel.2015.10.071 |
| WOS Subject Extended | Energy & Fuels ; Engineering |
| WOS Keyword | CATALYTIC FAST PYROLYSIS ; BIOMASS PYROLYSIS ; SHAPE-SELECTIVITY ; FLUIDIZED-BED ; ZEOLITE-BETA ; HYDROCARBONS ; OLEFINS ; ZSM-5 ; AROMATIZATION ; CONVERSION |
| Indexed By | SCI |
| Language | 英语 |
| WOS Subject | Energy & Fuels ; Engineering, Chemical |
| WOS ID | WOS:000364655000018 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/10890 |
| Collection | 中国科学院广州能源研究所 |
| Affiliation | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou, Guangdong, Peoples R China 2.Anhui Normal Univ, Coll Chem & Mat Sci, Wuhu, Peoples R China |
| Recommended Citation GB/T 7714 | Zhang, Qing,Tan, Jin,Wang, Tiejun,et al. Sorbitol transformation into aromatics: A comparative evaluation of Ni/HZSM-5 and Ni/H beta[J]. FUEL,2016,165. |
| APA | Zhang, Qing.,Tan, Jin.,Wang, Tiejun.,Zhang, Qi.,Ma, Longlong.,...&Weng, Yujing.(2016).Sorbitol transformation into aromatics: A comparative evaluation of Ni/HZSM-5 and Ni/H beta.FUEL,165. |
| MLA | Zhang, Qing,et al."Sorbitol transformation into aromatics: A comparative evaluation of Ni/HZSM-5 and Ni/H beta".FUEL 165(2016). |
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